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首页> 外文期刊>Journal of chemical crystallography >Crystal structure of chloritopentamminecobalt(III) tetracyanopalladate(II)
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Crystal structure of chloritopentamminecobalt(III) tetracyanopalladate(II)

机译:四氰基钯(II)的三氯叔戊胺钴(II)的晶体结构

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The X-ray crystal structure of [(NH_3)_5Co(ClO_2)][Pd(CN)_4] centre dot H_2O consists of two discrete complex ions and a water of hydration. The red crystals are triclinic, P1-bar, with lattice parameters a = 7.1992(5), b = 9.4873(7), c = 11.7752(8) A. #alpha# = 66.680(1), #beta# = 75.784(1), #gamma# = 82.203(1) deg, and Z = 2 giving a cell volume of 715.27(9) A~3 and a calculated density of 2.043 g/cm~3 at 293 deg. The chlorite ion is O-bonded to the cobalt atom with amine N-Co distances all equal. The chlorite ion is bent with a O-Cl-O angle of 110.8(2) deg and the Cl-O distances being 1.601(3) and 1.558(3) A, the longer value for the O atom also coordinated to Co. The Pd(CN)_4~(-2) ions are planar, C-coordinated and stack along the x-axis, separated by 3.599(1) A and alternatively rotated by 29.9(5) deg.
机译:[(NH_3)_5Co(ClO_2)] [Pd(CN)_4]中心点H_2O的X射线晶体结构由两个离散的复合离子和水合水组成。红色晶体是三斜晶的P1-bar,晶格参数a = 7.1992(5),b = 9.4873(7),c = 11.7752(8)A.#alpha#= 66.680(1),#beta#= 75.784( 1),#gamma#= 82.203(1)deg和Z = 2给出的单元格体积为715.27(9)A〜3和293度下的计算密度为2.043 g / cm〜3。亚氯酸根离子通过胺N-Co距离都相等而O键合至钴原子。亚氯酸根离子的O-Cl-O角为110.8(2)度,Cl-O距离为1.601(3)和1.558(3)A,O原子的较长值也与Co配位。 Pd(CN)_4〜(-2)离子是平面的,C坐标的,并且沿x轴堆叠,分隔为3.599(1)A,然后旋转29.9(5)度。

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