An unusual 2D → 3D metal-organic framework directed by rigid and flexible co-ligands

Liu J.-Q.; Wang Y.-Y.

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An unusual 2D → 3D metal-organic framework directed by rigid and flexible co-ligands

机译：由刚性和柔性共配体定向的不寻常的2D→3D金属有机框架

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Self-assembly of rigid dicarboxylate and flexible N-donor co-ligands in the presence of divalent metal ion affords a new polymer of [Cu(bpea)(bib)] _n (1) (bpea =biphenyle-thene-4,4′-dicarboxylate and bib = 1,4-bis(2- methyl-imidazol-1-yl)butane). The structure of 1 exhibits an unusual 2D → 3D motif with sql topology.

机译：在二价金属离子的存在下，刚性二羧酸盐和柔性N-给体共配体的自组装提供了[Cu（bpea）（bib）] _n（1）的新聚合物（bpea =联苯基-thene-4,4' -二羧酸盐和bib ＝ 1，4-双（2-甲基-咪唑-1-基）丁烷）。 1的结构显示具有SQL拓扑的不寻常的2D→3D主题。

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《Journal of chemical crystallography》 |2011年第12期|共5页
作者
Liu J.-Q.; Wang Y.-Y.;
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正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Entangled framework; Self-assembly; Topology;

机译：晶体结构;缠结框架;自组装;拓扑;

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专利

1. An unusual 2D → 3D metal-organic framework directed by rigid and flexible co-ligands [J] . Liu J.-Q., Wang Y.-Y. Journal of chemical crystallography . 2011,第12期

机译：由刚性和柔性共配体定向的不寻常的2D→3D金属有机框架
2. Two unusual 3D and 2D zinc coordination polymers containing 2D or 1D [Zn2(btec)]_n based on flexible bis(triazole) and rigid benzenetetracarboxylate co-ligands [J] . Shan Zhao, Xia Zhu, Ju Wang Inorganic Chemistry Communications . 2012,第Null期

机译：两种不同的3D和2D锌配位聚合物，它们包含基于柔性双（三唑）和刚性苯四羧酸酯共配体的2D或1D [Zn2（btec）] _ n
3. A New 3D Metal-Organic Framework Based on a Flexible and Rigid Co-Ligand: Synthesis, Structure, and Magnetic Properties [J] . Chun-Cheng Shi, Qi-Zhen Shi Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry . 2011,第7期

机译：基于柔性和刚性共配体的新型3D金属有机框架：合成，结构和磁性
4. Framework of integrating 2D points and curves for tracking of 3D non-rigid motion and structure [C] . Shin, M.C., Balasubramanian, . 2000

机译：集成2D点和曲线以跟踪3D非刚性运动和结构的框架
5. Rigid and Non-rigid 2D-3D Pose Estimation Using the Bhattacharyya Coefficient and a Locally Linear Embedding [D] . Lerner, Jeremy Neil. 2017

机译：使用Bhattacharyya系数和局部线性嵌入的刚性和非刚性2D-3D姿势估计
6. Competitive formation between 2D and 3D metal-organic frameworks: insights into the selective formation and lamination of a 2D MOF [O] . Sojin Oh, Jeehyun Park, Moonhyun Oh 2019

机译：2D和3D金属有机框架之间的竞争性形成：洞悉2D MOF的选择性形成和层压
7. Converting 3D rigid metal–organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation [O] . Yingdian He, Jin Shang, Qinfen Gu, 2015

机译：通过配体交换将3D刚性金属 - 有机框架（MOF）转换为2D柔性网络，用于增强CO2 / N2和CH4 / N2分离

An unusual 2D → 3D metal-organic framework directed by rigid and flexible co-ligands

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