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Synthesis and crystal structure of a pure inorganic network based tetra-sodium capped sandwich-type polyanion

机译:基于纯无机网络的四钠封端三明治型聚阴离子的合成和晶体结构

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摘要

The synthesis and single-crystal structure of a Na-salt compound Na 10[Co4(OH2)2(AsW9O 34)2]?32H2O (1) was reported. Compound 1 crystallizes in triclinic system, space group P-1, with the lattice parameters: a = 11.6040(10) ?, b = 12.9361(13) ?, c = 17.396(2) ?, α = 97.4120(10)°, β = 106.8590(10)°, γ = 111.867(2)° and Z = 1. Compound 1 consists of a pure inorganic network based on tetra-sodium capped sandwich-type anionic clusters [Co4(OH2) 2(AsW9O34)2]10- bridged through Na-OH2 subunits. The thermogravimetric and electrochemistry measurements had also been studied. Graphical Abstract: A pure inorganic network built upon tetra-sodium capped sandwich-type polyanions and Na-O-Na units.
机译:报告了钠盐化合物Na 10 [Co4(OH2)2(AsW9O 34)2]→32H2O(1)的合成和单晶结构。化合物1在三斜晶系空间群P-1中结晶,晶格参数为:a = 11.6040(10)α,b = 12.9361(13)α,c = 17.396(2)α,α= 97.4120(10)°, β= 106.8590(10)°,γ= 111.867(2)°,Z =1。化合物1由基于四钠封端的三明治型阴离子簇[Co4(OH2)2(AsW9O34)2]的纯无机网络组成。 10-通过Na-OH2亚基桥接。还研究了热重和电化学测量。图形摘要:基于四钠封端的三明治型聚阴离子和Na-O-Na单元构建的纯无机网络。

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