The use of carborane anions in coordination polymers and extended solids

Hardie MJ

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The use of carborane anions in coordination polymers and extended solids

机译：碳硼烷阴离子在配位聚合物和扩展固体中的使用

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The use of carboranes as counter-anions for metal-organic frameworks or coordination polymers is reviewed. While carboranes are weakly coordinating they can form interactions to Ag(I) as well as other metal centers. Thus carboranes may have one of a number of roles in transition metal networks: as a non-coordinating templating counter-anion; as a bulky terminal ligand, and thus topologically trivial but likely to be structure-directing to some degree; or as a bridging ligand.

机译：综述了碳硼烷作为金属有机骨架或配位聚合物的抗衡阴离子的用途。尽管碳硼烷的配位能力较弱，但它们可以与Ag（I）以及其他金属中心形成相互作用。因此，碳硼烷在过渡金属网络中可能具有多种作用之一：作为非配位模板抗衡阴离子;作为庞大的末端配体，因此拓扑上很琐碎，但在某种程度上可能是结构指导的;或作为桥接配体。

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《Journal of chemical crystallography》 |2007年第1期|共12页
作者
Hardie MJ;
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正文语种 eng
中图分类晶体学;
关键词
coordination polymers; metal-organic frameworks; carborane anions; METAL-ORGANIC FRAMEWORKS; LANTHANIDE AQUO IONS; COBALT(III) BIS(DICARBOLLIDE); STRUCTURAL-CHARACTERIZATION; SILVER(I) COMPLEXES; HOST MOLECULE; CYCLOTRIVERATRYLENE; NETWORKS; CHEMISTRY; CRYSTAL;

机译：配位聚合物;金属-有机骨架;碳硼烷阴离子;金属-有机骨架;镧系元素水离子;钴（III）双（二碳）;结构表征;银（I）络合物;主体分子;环戊腈;网络;

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1. The use of carborane anions in coordination polymers and extended solids [J] . Hardie MJ Journal of chemical crystallography . 2007,第1期

机译：碳硼烷阴离子在配位聚合物和扩展固体中的使用
2. Coordination Polymers with Carborane Anions:Silver Dinitrile Complexes [J] . Aleema Westcott, Nina Whitford, Michaele J.Hardie Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第12期

机译：碳硼烷阴离子配位聚合物：银双金属配合物
3. Mechanochemical solid state anion-exchange of lead(II) coordination polymers via an intermediate coordination polymer; new precursors for the preparation of PbBr_2/Pb_3O_2Br_2, PbBr(OH) and PbO nanoparticles [J] . Lida Hashemi, Ali Morsali, Sang Woo Joo Dalton transactions: An international journal of inorganic chemistry . 2014,第4期

机译：铅（II）配位聚合物通过中间配位聚合物的机械化学固态阴离子交换;制备PbBr_2 / Pb_3O_2Br_2，PbBr（OH）和PbO纳米粒子的新前体
4. Irreversible Crystal to Crystal Transformation of Nano Lead(ll) Coordination Polymer by Solid State Anion-replacement [C] . Ali Morsali, Vahid Safarifard International Conference on Advanced Material and Manufacturing Science . 2014

机译：不可逆晶体通过固态阴离子置换纳米铅（LL）配位聚合物的晶体变换
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. Four Novel Zn (II) Coordination Polymers Based on 4′-Ferrocenyl-32′:6′3′′-Terpyridine: Engineering a Switch from 1D Helical Polymer Chain to 2D Network by Coordination Anion Modulation [O] . Lufei Xiao, Dajun Wu, Xuchun Wang, 2017

机译：基于4-二茂铁基-32：63-三联吡啶的四种新型Zn（II）配位聚合物：通过配位阴离子调制将一维螺旋聚合物链转换为二维网络
7. One-Dimensional Coordination Polymers of Bis(3-pyridyl-acrylamido)ethane: Influence of Anions and Metal Ions on Their Solid State 2 + 2 Photochemical Polymerization and Dimerization Reactions [O] . -1

机译：双（3-吡啶基 - 丙烯酰基）乙烷的一维配位聚合物：阴离子和金属离子对其固态的影响2 + 2光化学聚合和二聚化反应

The use of carborane anions in coordination polymers and extended solids

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