Synthesis and Crystal Structure of Bis (N,N,N',N'-tetramethylethylendiammonium) Octaiodo Pentachloroantimonate (III)

Kharrat H.; Kamoun S.; Ayedi H.; Driss A.

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Synthesis and Crystal Structure of Bis (N,N,N',N'-tetramethylethylendiammonium) Octaiodo Pentachloroantimonate (III)

机译：双（N，N，N'，N'-四甲基乙基endiummmonium）Octaiodo五氯锑酸酯的合成和晶体结构

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The synthesis and Crystal structure are given for the bis (N,N,N',N'-tetramethylethylendiammonium) octaiodo pentachloroantimonate (III) salt. An X-ray investigation has shown that the title compound crystallizes in a monoclinic system, space group P21/m with the following lattice parameters a = 9.786(2) ?, b = 14.024(5) ?, c = 14.336(3) ?, β = 91.35(2)o and Z = 2. The structure was solved from 3085 independent reflections with R_1 = 0.0402 and wR_2 = 0.0952 and refined with 152 parameters. The structure shows a layer arrangement perpendicular to the b-axis: planes of [SbCl_5]~(2-), I_3~- and I_5~- anions alternateith planes of [(CH_2)_2(NH(CH_3)_2)_2]~(2+) cations. The [SbCl_5]~(2-) square pyramids present an active lone electron pair (LEP) on the Sb atoms and they are interconnected by means of N-H···Cl hydrogen bond originating from [(CH_2)_2(NH(CH_3)_2)_2]~(2+) entities. The polyiodides (I_3~- and I_5~-) anions form a planer zigzag polymeric chains via I···I linking interactions. These chains are linked to the [SbCl_5]~(2-) anions by a long range contact

机译：给出了双（N，N，N'，N'-四甲基乙基endiummmonium）十溴代五氯锑酸盐（III）盐的合成和晶体结构。 X-射线研究表明，标题化合物在单斜晶系空间群P21 / m中结晶，其晶格参数为a ＝ 9.786（2）θ，b ＝ 14.024（5）θ，c ＝ 14.336（3）θ。，β= 91.35（2）o，Z =2。该结构是根据R_1 = 0.0402和wR_2 = 0.0952的3085个独立反射进行求解的，并使用152个参数进行了改进。该结构显示了垂直于b轴的层排列：[SbCl_5]〜（2-），I_3〜-和I_5〜-阴离子的交替平面为[（CH_2）_2（NH（CH_3）_2）_2]〜的平面）。（2+）个阳离子。 [SbCl_5]〜（2-）方金字塔在Sb原子上存在一个活动的孤电子对（LEP），它们通过源自[[CH_2] _2（NH（CH_3） _2）_2]〜（2+）个实体。聚碘离子（I_3〜-和I_5〜-）通过I··I连接相互作用形成平面锯齿形聚合物链。这些链通过长距离接触与[SbCl_5]〜（2-）阴离子连接

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《Journal of chemical crystallography》 |2010年第9期|共5页
作者
Kharrat H.; Kamoun S.; Ayedi H.; Driss A.;
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正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Chloroantimonates (III); Polyiodides;

机译：晶体结构;氯锑酸盐（III）;聚碘化物;

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Synthesis and Crystal Structure of Bis (N,N,N',N'-tetramethylethylendiammonium) Octaiodo Pentachloroantimonate (III)

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