Synthesis, X-ray Crystallographic, Electrochemical, and Spectroscopic Studies of Bis-(1,10-phenanthroline)(2,2'-bipyridine)cobalt(III) Hexafluorophosphate

Lawrence Mark A. W.; McMillen Colin D.; Gurung Raj K.; Celestine Michael J.; Arca Jessa F.; Holder Alvin A.

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Synthesis, X-ray Crystallographic, Electrochemical, and Spectroscopic Studies of Bis-(1,10-phenanthroline)(2,2'-bipyridine)cobalt(III) Hexafluorophosphate

机译：双-（1,10-菲咯啉）（2,2'-联吡啶）钴（III）六氟磷酸酯的合成，X射线晶体学，电化学和光谱研究

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The synthesis, X-ray crystallographic, electrochemical, and spectroscopic studies of bis-(1,10-phenanthroline)(2,2'-bipyridine)cobalt(III) hexafluorophosphate with acetone solvent of crystallization ([Co(phen)(2)(bpy)](PF6)(3)center dot 1.6(CH3)(2)CO) is reported. The compound crystallized in a monoclinic space group P2(1) with a = 13.215(3) , b = 17.823(4) , c = 19.823(4) , beta = 96.80(3)A degrees and V = 4636.1(16) (3) with Z = 4. The cobalt(III) metal center has a slightly distorted octahedral geometry. 1,10-Phenanthroline and 2,2'-bipyridine ligands were generally planar, and did not exhibit pi-pi overlap. The packing of the cations was stabilized by hydrogen bonding with hexafluorophosphate anions. The electrochemical studies revealed the Co-III/II, Co-II/I and Co-I/0 redox couples at E (1/2) = +0.32, -0.91 and -1.61 V (vs AgCl/Ag) respectively in acetonitrile. Co-59 NMR spectroscopic studies revealed that the [Co(phen)(2)(bpy)](PF6)(3)center dot 0.5(C2H5)(2)O species has a chemical shift of 6900 ppm in DMSO-d (6).

机译：双（1,10-菲咯啉）（2,2'-联吡啶）钴（III）六氟磷酸盐钴（III）的结晶，丙酮溶剂的合成，X射线晶体学，电化学和光谱学研究报告（bpy）]（PF6）（3）中心点1.6（CH3）（2）CO）。该化合物在单斜空间群P2（1）/ n中结晶，其中a = 13.215（3），b = 17.823（4），c = 19.823（4），β= 96.80（3）A度和V = 4636.1（16））（3），Z =4。钴（III）金属中心的八面体几何形状略有变形。 1,10-菲咯啉和2,2'-联吡啶配体通常是平面的，没有pi-pi重叠。阳离子的堆积通过与六氟磷酸根阴离子的氢键键合而稳定。电化学研究表明乙腈中E（1/2）= + 0.32，-0.91和-1.61 V（vs AgCl / Ag）的Co-III / II，Co-II / I和Co-I / 0氧化还原对。 Co-59 NMR光谱研究表明[Co（phen）（2）（bpy）]（PF6）（3）中心点0.5（C2H5）（2）O物种在DMSO-d中的化学位移为6900 ppm（ 6）。

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《Journal of chemical crystallography》 |2015年第9期|共7页
作者
Lawrence Mark A. W.; McMillen Colin D.; Gurung Raj K.; Celestine Michael J.; Arca Jessa F.; Holder Alvin A.;
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正文语种 eng
中图分类晶体学;
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Cobalt(III); 1; 10-Phenanthroline; 2; 2 '-Bipyridine; X-ray crystallography; Electrochemistry; Co-59 NMR;

机译：钴（III）;1;10-菲咯啉;2;2'-联吡啶;X射线晶体学;电化学;Co-59 NMR;

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1. Synthesis, X-ray Crystallographic, Electrochemical, and Spectroscopic Studies of Bis-(1,10-phenanthroline)(2,2'-bipyridine)cobalt(III) Hexafluorophosphate [J] . Lawrence Mark A. W., McMillen Colin D., Gurung Raj K., Journal of chemical crystallography . 2015,第8a9期

机译：双-（1,10-菲咯啉）（2,2'-联吡啶）钴（III）六氟磷酸酯的合成，X射线晶体学，电化学和光谱研究
2. Pulse radiolytic studies on cis-dichlorobis-(2,2'-bipyridine)cobalt(III)and cis-dichlorobis-(1,10-phenanthroline)cobalt(III)complexes [J] . Smita Ghosh, Vitthal A Kawade, Avinash V Sapre Indian Journal of Chemistry, Section A. Inorganic, Physical, Theoretical & Analytical . 2008,第5期

机译：顺-二氯双（2,2'-联吡啶）钴（III）和顺-二氯双-（1,10-菲咯啉）钴（III）配合物的脉冲辐射研究
3. Synthesis, Infrared Spectroscopic, and Cyclic Voltammetric Studies on 1,10-Phenanthroline and 2,2'-Bipyridine Adducts of Bis(4-morpholinecarbodithioato-S,S')zinc(II) and Single-Crystal Structure Determination of (2,2'-Bipyridine)bis(4-morpholinecarbodithioato-S,S') zinc(II) [J] . S. Thirumaran, K. Ramalingam, G. Bocelli, Phosphorus, Sulfur, and Silicon and the Related Elements . 2009,第2期

机译：双（4-吗啉碳二硫代-S，S'）锌（II）的1,10-菲咯啉和2,2'-联吡啶加合物的合成，红外光谱和循环伏安研究和（2,2的单晶体结构测定'-联吡啶）双（4-吗啉碳二硫代-S，S'）锌（II）
4. Synthesis and Thermal Characterization of the Erbium(Ⅲ) Complex With β-diketone Ligands and 1,10-Phenanthroline or 2,2-Bipyridine [C] . Crislene R. da S. Morais, Wilton S. Lopes, Ant?nio G. de Souza, Proceedings of the 31st annual conference of the North American Thermal Analysis Society(NATAS) . 2003

机译：含β-二酮配体和1,10-菲咯啉或2,2-联吡啶的Er（Ⅲ）配合物的合成与热表征
5. Spectroscopic and Electrochemical Studies of [Ru(1,10-phenanthroline) 2(4,4'- dihydroxy-2,2'-bipyridine)]2+ and Related Complexes. [D] . Kuhn, Ashley E. 2017

机译：[Ru（1,10-phenothroline）2（4,4'-dihydroxy-2,2'-bipyridine）] 2+及其相关配合物的光谱和电化学研究。
6. Stabilization of tetrameric metavanadate ion by tris(110-phenanthroline)cobalt(III): Synthesis spectroscopic and X-ray structural study of Co(phen)33(V4O12)2Cl·27H2O [O] . RAJ PAL SHARMA, AJNESH SINGH, PALOTH VENUGOPALAN, -1

机译：TRIS（110-菲咯啉）钴（III）的四聚体甲烷酸盐离子的稳定化：CO（phen）3 3（V4O12）2CL·27H2O的合成光谱和X射线结构研究
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）
8. Electropolymerization of Ruthenium Bis(1,10-phenanthroline)(4-methyl-4'vinyl-2,2'-bipyridine) Complexes through Direct Attack on the Ligand Ring System [R] . Guarr, T. F., Anson, F. C. 1987

机译：直接攻击配体环系统对双（1,10-菲咯啉）（4-甲基-4'-乙烯基-2,2'-联吡啶）配合物的电聚合

Synthesis, X-ray Crystallographic, Electrochemical, and Spectroscopic Studies of Bis-(1,10-phenanthroline)(2,2'-bipyridine)cobalt(III) Hexafluorophosphate

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