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首页> 外文期刊>Journal of chemical crystallography >Redetermination of the structure of bis[chloro-2-(2-hydroxy-4,5-dimethylphenylazo)-5,5-dimethyl-4,5,6,7-tetrahydrobenzothiazol-7-on] copper(II) complex
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Redetermination of the structure of bis[chloro-2-(2-hydroxy-4,5-dimethylphenylazo)-5,5-dimethyl-4,5,6,7-tetrahydrobenzothiazol-7-on] copper(II) complex

机译:重新测定双[氯-2-(2-羟基-4,5-二甲基苯基偶氮)-5,5-二甲基-4,5,6,7-四氢苯并噻唑-7-on]铜(II)配合物的结构

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摘要

The crystal structure of C_(17)H_(18)ClCuN_3O_2S (M = 854.78, monoclinic, P2_1/c, a = 8.316(2), b = 18.461(4), c = 11.774(2) A, β = 99.64(3)°, V = 1782.0(7) A~3, Z = 4) is formed by dimeric molecules [C_(17)H_(18)ClCuN_3O_2S]_2 with two monomeric units linked together by two chlorine atoms, an oxygen atom, the azo nitrogen atom attached to the benzene ring, and the nitrogen atom of the thiazole ring, in the form of a distorted tetragonal pyramid.
机译:C_(17)H_(18)ClCuN_3O_2S的晶体结构(M = 854.78,单斜晶系,P2_1 / c,a = 8.316(2),b = 18.461(4),c = 11.774(2)A,β= 99.64( 3)°,V = 1782.0(7)A〜3,Z = 4)由二聚体分子[C_(17)H_(18)ClCuN_3O_2S] _2组成,两个单体单元通过两个氯原子,一个氧原子连接在一起,连接到苯环的偶氮氮原子和噻唑环的氮原子呈扭曲的四角锥形式。

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