Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H_3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

M. John Plater; Mark R. St J. Foreman; Janet M. S. Skakle

首页> 外文期刊>Journal of chemical crystallography >Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H_3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

【24h】

Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H_3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

机译：水热合成[Mn（HTPO）（BIPY）]（H_3TPO =三-（4-羧基苯基）氧化膦）：交联的配位聚合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group is P-1 with a = 11.6767(8) A, b = 10.8680(8) A and c = 11.4232(8) A; α = 92.301(2), β = 106.932(2)° and γ = 103.2390(10)°; V = 1341.02(16) A~3; Z = 2.

机译：报告了标题化合物的水热合成和晶体结构。该结构由一维环状链组成，其中HTPO配体通过磷酰基和两个羧基氧与锰原子结合。羧酸基团氢键合到相邻的链上，形成2-D氢键合网络。晶体为三斜晶，空间群为P-1，a = 11.6767（8）A，b = 10.8680（8）A，c = 11.4232（8）A; α= 92.301（2），β= 106.932（2）°和γ= 103.2390（10）°; V = 1341.02（16）A〜3; Z = 2。

著录项

来源
《Journal of chemical crystallography》 |2000年第7期|共5页
作者
M. John Plater; Mark R. St J. Foreman; Janet M. S. Skakle;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
coordination polymer; manganese; hydrogen bonding; hydrothermal synthesis;

机译：配位聚合物锰氢键水热合成;

相似文献

外文文献
中文文献
专利

1. Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H_3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer [J] . M. John Plater, Mark R. St J. Foreman, Janet M. S. Skakle Journal of chemical crystallography . 2000,第7期

机译：水热合成[Mn（HTPO）（BIPY）]（H_3TPO =三-（4-羧基苯基）氧化膦）：交联的配位聚合物
2. Hydrothermal synthesis of [Co-3(TPO)(2)(bipy)(2)(H2O)(6)]center dot 2.4 H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer [J] . Plater MJ., Gelbrich T., Hursthouse MB., Journal of chemical crystallography . 2000,第3期

机译：[Co-3（TPO）（2）（bipy）（2）（H2O）（6）]中心点2.4 H2O的水热合成（H3TPO =三-（4-羧基苯基）氧化膦）。一维双链配位聚合物
3. Heteropolymetallic assemblies constructed from homometallic coordination polymers and paramagnetic metal-containing anions. (Synthesis, crystal structure and magnetic properties of [Mn(4,4'-bipyridine-N,N'-dioxide) (H_2O_4)][Cr(bipy)(C_2O_4)_2]_2·8H_2O) [J] . Sandra Bruda, Marius Andruh, Herbert W.Roesky, Inorganic Chemistry Communications . 2001,第2期

机译：由均金属配位聚合物和含顺磁性金属的阴离子构成的杂多金属组装体。（[Mn（4,4'-联吡啶-N，N'-二氧化物）（H_2O_4）] [Cr（bipy）（C_2O_4）_2] _2·8H_2O的合成，晶体结构和磁性
4. Hydrothermal Synthesis of a New Oxalato-bridged Binuclear Complex:Cr2(bipy)4(C2O4)(SO4)2·(bipy)0.5·H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：水热合成新型草酸桥联双核络合物：Cr2（bipy）4（C2O4）（SO4）2·（bipy）0.5·H2O
5. The Synthesis of New Coordination Polymer Using Crystal Engineering, Self-Assembly, and Hydrothermal Synthesis [D] . Fu, Lei 2018

机译：利用晶体工程，自组装和水热合成法合成新型配位聚合物
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis, Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 2,2-Dimethylpentanedioic Acid(2dmepdaH 2 ) and 3,3-Dimethylpentanedioic acid(3dmepdaH 2 ): X-Ray Crystal Structures of [Cu(3dmepda)(bipy)] 2 ⋅ 6H 2 O and [Cu(2dmepda)(bipy)(EtOH)] 2 ⋅4EtOH( bipy=2, 2 ′ Bipyridine) [O] . 2006

机译：2,2-二甲基戊二酸（2 dmepda H 2 ）和3,3-二甲基戊二酸（3 < small.letters> dmepda H 2 ）：[C u （3 dmepda ）（ bipy ）] 2 ⋅ 6H 2 O 和[C < small.letters> u （2 dmepda ）（ bipy ）（E t OH）] 2 ⋅ 4 EtOH （ bipy = 2 ， 2 ' 联吡啶）
8. ULTRAVIOLET SPECTROPHOTOMETRIC DETERMINATION OF URANIUM Separation of Uranium from Bismuth Using Tris-(2-ethylhexyl)phosphine Oxide [R] . Arno H. A. Heyn, Gurupada Banerjee 1959

机译：三（2-乙基己基）氧化膦紫外分光光度法测定铀从铋中分离铀

Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H_3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer

摘要

著录项

相似文献

相关主题

期刊订阅