Correlation of Vapor-Liquid Equilibria of Binary Systems Containing Carboxylic Acid by Using Wilson Equation with Parameters Estimated from Pure-Component Properties

Shigetoshi Kobuchi; Kei Takakura; Setsuko Yonezawa

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Correlation of Vapor-Liquid Equilibria of Binary Systems Containing Carboxylic Acid by Using Wilson Equation with Parameters Estimated from Pure-Component Properties

机译：用具有纯组分性质的参数的Wilson方程对含羧酸二元体系的汽液平衡进行关联

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A simple method for estimating the Wilson parameters from pure component properties alone previously proposed has been adopted to predict the vapor-liquid equilibria of binary systems containing carboxylic acids such as acetic acid. Carboxylic acid vapors are characterized by the presence of large amounts of dimers.The binary mixtures of non-associating substance+carboxylic acid and carboxylic acid+carboxylic acid have been studied. The prediction performances obtained are examined and discussed.

机译：已经采用了一种简单的方法，该方法仅由先前提出的仅从纯组分性质中估计Wilson参数的方法，即可预测包含羧酸（例如乙酸）的二元体系的气液平衡。羧酸蒸气的特征是存在大量的二聚体。研究了非缔合物质+羧酸和羧酸+羧酸的二元混合物。对获得的预测性能进行了检查和讨论。

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《Journal of Chemical Engineering of Japan》 |2013年第3期|共7页
作者
Shigetoshi Kobuchi; Kei Takakura; Setsuko Yonezawa;
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正文语种 eng
中图分类一般性问题;
关键词
Wilson Parameter; Vapor-Liquid Equilibrium; Binary System; Carboxylic Acid; Solubility Parameter; Molar Volume; Pure-Component Property;

机译：威尔逊参数;汽-液平衡;二元体系;羧酸;溶解度参数;摩尔体积;纯组分性质;

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1. Correlation of Vapor-Liquid Equilibria of Binary Systems Containing Carboxylic Acid by Using Wilson Equation with Parameters Estimated from Pure-Component Properties [J] . Shigetoshi Kobuchi, Kei Takakura, Setsuko Yonezawa Journal of Chemical Engineering of Japan . 2013,第1a3期

机译：用具有纯组分性质的参数的Wilson方程对含羧酸二元体系的汽液平衡进行关联
2. Prediction of Vapor-Liquid Equilibria of Binary Systems at Reduced Pressures by Using Wilson Equation with Parameters Estimated from Pure-Component Properties [J] . Shigetoshi Kobuchi, Setsuko Yonezawa Journal of Chemical Engineering of Japan . 2014,第1a3期

机译：使用具有纯组分性质估计参数的Wilson方程预测减压下的二元系统蒸气-液体平衡
3. Prediction of Isothermal Vapor-Liquid Equilibria of Binary Systems by Using Wilson Equation with Parameters Estimated from Pure-Component Properties [J] . Kobuchi Shigetoshi, Yonezawa Setsuko Journal of Chemical Engineering of Japan . 2014,第8a12期

机译：用参数估计纯组分性质的Wilson方程预测二元系统的等温蒸气-液体平衡
4. MEASUREMENTS AND MODELING OF VAPOR-LIQUID EQUILIBRIA IN BINARY SYSTEMS OF METHANE + {N-C_5, NC_6, OR BTEX COMPOUNDS) AT CRYOGENIC TEMPERATURES AND HIGH PRESSURES [C] . Eric F. May, Sean McCallum, Mohamed E. Kandil, . 2011

机译：低温和高压下甲烷+ {N-C_5，NC_6或BTEX化合物）的二元体系中气液平衡的测量和建模
5. Estimating correlation parameters in cluster intervention trials with binary responses using estimating equations. [D] . Lu, Bing. 2005

机译：使用估算方程估算具有二元响应的聚类干预试验中的相关参数。
6. Molecular simulation data for the vapor-liquid phase equilibria of binary mixtures of HFO-1123 with R-32 R-1234yf R-1234ze(E) R-134a and CO2 and their modelling by the PCP-SAFT equation of state [O] . Gabriele Raabe 2019

机译：HFO-1123与R-32R-1234yfR-1234ze（E）R-134a和CO2的二元混合物的汽液相平衡的分子模拟数据及其通过状态PCP-SAFT方程进行建模
7. Correlation of Vapor-Liquid Equilibria for Commonly Used Binary Systems in Supercritical Fluid Extraction Processes [O] . Saeid Atashrouz, Hamed Mirshekar, Hamid Bagheri 2013

机译：超临界流体提取过程中常用二元系统的蒸汽液平衡的相关性
8. Temperature Dependence of Wilson Coefficients: Vapor-Liquid Equilibria of Aqueous Ammonia [R] . Field, P. E. , Combs, R. J. 2001

机译：Wilson系数的温度依赖性：氨水的汽液平衡

Correlation of Vapor-Liquid Equilibria of Binary Systems Containing Carboxylic Acid by Using Wilson Equation with Parameters Estimated from Pure-Component Properties

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