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Synthesis and photochemical transformations of a few olefin-appended 11,12-dibenzoyldibenzobarrelenes

机译:几种烯烃附加的11,12-二苯甲酰基二苯并戊烯的合成与光化学转化

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摘要

Several olefin-appended dibenzobarrelenes have been synthesised by Diels-Alder reaction between 9-alkenylanthracenes and dibenzoylacetylene under carefully controlled conditions and their photochemistry was examined. Olefin appendages acted as efficient quenchers of the triplet state of these barrelenes.
机译:通过9-烯基蒽与二苯甲酰基乙炔之间的Diels-Alder反应,在严格控制的条件下合成了几种烯烃加成的二苯并戊烯并对其光化学进行了研究。烯烃附件充当这些桶烯的三重态的有效猝灭剂。

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