Raney Ni–Al alloy mediated hydrodehalogenation and aromatic ring hydrogenation of halogenated phenols in aqueous medium

Guo-Bin Liu; Hong-Yun Zhao; Jie Zhang; Thies Thiemann

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Raney Ni–Al alloy mediated hydrodehalogenation and aromatic ring hydrogenation of halogenated phenols in aqueous medium

机译：Raney Ni-Al合金介导的水性介质中卤代酚的加氢脱卤和芳环加氢

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摘要

Raney Ni–Al alloy in a dilute aqueous alkaline solution has been shown to be a very powerful reducing agent and is highly effective for the reductive dehalogenation of polyhalogenated phenols and aromatic ring hydrogenation of phenols to the corresponding cyclohexanols.

机译：阮内镍铝合金在稀碱性水溶液中已被证明是一种非常有效的还原剂，对于多卤代酚的还原脱卤和酚的芳环加氢生成相应的环己醇非常有效。

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《Journal of chemical research: reviews and research papers from all branches of chemistry》 |2009年第6期|共3页
作者
Guo-Bin Liu; Hong-Yun Zhao; Jie Zhang; Thies Thiemann;
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正文语种 eng
中图分类化学;
关键词
Raney Ni-Al alloy; phenols; reduction; detoxification; aqueous alkaline solution; cyclohexanols;

机译：Raney Ni-Al合金;酚;还原;解毒;碱性水溶液;环己醇;

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1. Raney Ni–Al alloy mediated hydrodehalogenation and aromatic ring hydrogenation of halogenated phenols in aqueous medium [J] . Guo-Bin Liu, Hong-Yun Zhao, Jie Zhang, Journal of chemical research: reviews and research papers from all branches of chemistry . 2009,第6期

机译：Raney Ni-Al合金介导的水性介质中卤代酚的加氢脱卤和芳环加氢
2. Organic reaction in water. Part 3:~1 A facile method for reduction of aromatic rings a Raney Ni-Al alloy in dilute aqueous alkaline solution under mild conditions [J] . Tsukinoki Takehito, Kanda Tadashige, Liu Guo-Bin Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第31期

机译：在水中的有机反应。第3部分：〜1在温和条件下在稀碱水溶液中还原阮内镍铝合金芳环的简便方法
3. A Review on the Recent Advances in the Reductions of Carbon-Carbon/Oxygen Multiple Bonds Including Aromatic Rings Using Raney Ni-Al Alloy or Al Powder in the Presence of Noble Metal Catalysts in Water [J] . Rayhan Ummey, Kowser Zannatul, Islam Md. Nurul, Topics in Catalysis . 2018,第7a8期

机译：关于碳碳/氧气多键减少最近进步的综述，所述碳碳/氧气多键在水中贵金属催化剂存在下使用Raney Ni-Al合金或Al粉末的芳香环
4. ELECTROCATALYTIC HYDROGENATION OF SUBSTITUTED NAPHTHALENES AT RANEY Ni ELECTRODES IN AQUEOUS MEDIA [C] . Stephane Jobin, Jean Lessard International Symposium on Mechanistic and Synthetic Aspects of Organic and Biological Electrochemistry . -1

机译：介质中阮内尼电极上萘取代萘的电催化加氢
5. Characterization and phylogenetic analysis of a phenol and halogenated aromatic compound degrading microbial consortium. [D] . Rehfuss, Marc Y. 2004

机译：苯酚和卤代芳族化合物降解微生物财团的表征和系统发育分析。
6. Comparative study on catalytic hydrodehalogenation of halogenated aromatic compounds over Pd/C and Raney Ni catalysts [O] . Xuanxuan Ma, Sujing Liu, Ying Liu, -1

机译：Pd / C和Raney Ni催化剂上卤代芳族化合物催化加氢脱卤的比较研究
7. Comparative study on catalytic hydrodehalogenation of halogenated aromatic compounds over Pd/C and Raney Ni catalysts [O] . Ma, XX, Liu, SJ, Liu, Y, 2016

机译：Pd / C和Raney Ni催化剂上卤代芳族化合物催化加氢脱卤的比较研究
8. Photolytic and Partitioning Behavior of Polynuclear Aromatic Compounds, Aromatic Amines, and Phenols in Aqueous Coal Oil [R] . Picel, K. C., Stamoudis, V. C., Simmons, M. S. 1985

机译：含水煤油中多核芳香族化合物，芳香胺和酚类的光解和分配行为

Raney Ni–Al alloy mediated hydrodehalogenation and aromatic ring hydrogenation of halogenated phenols in aqueous medium

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