Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis 2. Competitive Asorption of the Reactants and Products in the Friedel-Crafts Acetylations of Anisole and Toluene

E.G.Derouane; G.Crehan; D.Bethell

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Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis 2. Competitive Asorption of the Reactants and Products in the Friedel-Crafts Acetylations of Anisole and Toluene

机译：精细化工合成中作为固体溶剂的沸石催化剂2.苯甲醚和甲苯的Friedel-Crafts乙酰化反应中反应物和产物的竞争性吸附

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The liquid -phase acetylation of anisole by acetic anhydride and isopropenyl acetate that of toluene by acetic anhydride, using zeolites HBEA, HMFI, and HRAU as catalysts ,were carried otu under batch conditions using various molar rations of the reactants without added solvent

机译：使用沸石HBEA，HMFI和HRAU作为催化剂，通过乙酸酐对苯甲醚进行液相乙酰化，乙酸酐对甲苯进行乙酸乙酰丙酯的液相乙酰化。

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《Journal of Catalysis》 |2001年第2期|共14页
作者
E.G.Derouane; G.Crehan; D.Bethell;
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正文语种 eng
中图分类高分子化学（高聚物）;催化反应过程;物理化学（理论化学）、化学物理学;
关键词
heterogenous catalysis; zeolite zeolite dealumination; competitive adsorption Friedel-Carfts reaction; solvent effect; fine chemicals;

机译：非均相催化;沸石脱铝;竞争吸附Friedel-Carfts反应;溶剂效应;精细化工;

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1. Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis 2. Competitive Asorption of the Reactants and Products in the Friedel-Crafts Acetylations of Anisole and Toluene [J] . E.G.Derouane, G.Crehan, D.Bethell Journal of Catalysis . 2001,第2期

机译：精细化工合成中作为固体溶剂的沸石催化剂2.苯甲醚和甲苯的Friedel-Crafts乙酰化反应中反应物和产物的竞争性吸附
2. Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis [J] . E. G. Derouane, C. J. Dillon, D. Bethell, Journal of Catalysis . 1999,第1期

机译：精细合成中作为固体溶剂的沸石催化剂
3. Zeolite-catalyzed Friedel-Crafts acylation of aromatics:Ⅰ.Synthesis of 4-acyl anisole with a HY catalyst [J] . 中国化学快报（英文版） . 1996,第002期

机译：沸石催化芳烃的Friedel-Crafts酰化反应：Ⅰ.HY催化剂合成4-酰基茴香醚
4. Novel delaminated zeolites are more active acid catalysts than conventional zeolites and mesoporous Al/MCM-41 for the synthesis of fine chemicals [C] . María J. Climent, Avelino Corma, Vicente Fornés, IZC;International zeolite conference . 2001

机译：新型分层沸石比常规沸石和介孔Al / MCM-41具有更高的活性酸催化剂，可用于合成精细化学品
5. Toluene methylation with methanol over bi-porous acidic and basic zeolite catalysts: Synthesis, characterization and kinetic modeling. [D] . Olaiya, Alabi Wahab. 2012

机译：双孔酸性和碱性沸石催化剂上甲醇甲醇甲苯甲基化：合成，表征和动力学模型。
6. Minimization of Amounts of Catalyst and Solvent in NHC-CatalyzedBenzoin Reactions of Solid Aldehydes: Mechanistic Consideration ofSolid-to-Solid Conversion and Total Synthesis of Isodarparvinol B [O] . Kenta Iwai, Masakazu Ono, Yoshiko Nanjo, 2020

机译：NHC催化中催化剂和溶剂的量最少固体醛的安息香反应：机理的机械考虑异黄柏醇B的固-固转化和全合成
7. A Novel Friedel-Crafts Acylation Reaction of Anisole for Production of 4-Methoxyacetophenone with High Selectivity and Sufficient Reusability of Mordenite Zeolite Catalyst [O] . Makoto Makihara, Kenichi Komura 2017

机译：一种新的Friedel-Craftsα-抗氧氧酮的酰化反应，用于生产4-甲氧基苯酮，具有高选择性和充分的Mordenite沸石催化剂的可重用性

Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis 2. Competitive Asorption of the Reactants and Products in the Friedel-Crafts Acetylations of Anisole and Toluene

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