Hydrothermal synthesis, crystal structure, and electrochemical property of a new 3-D coordination polymer based on benzene-1,2,4,5-tetracarboxylate bridging ligand: [Cu_2(btec)(en)_2]_n

HONGYAN LIN; HAILIANG HU; XIULI WANG; BAO MU; JIN LI

首页> 外文期刊>Journal of Coordination Chemistry >Hydrothermal synthesis, crystal structure, and electrochemical property of a new 3-D coordination polymer based on benzene-1,2,4,5-tetracarboxylate bridging ligand: [Cu_2(btec)(en)_2]_n

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Hydrothermal synthesis, crystal structure, and electrochemical property of a new 3-D coordination polymer based on benzene-1,2,4,5-tetracarboxylate bridging ligand: [Cu_2(btec)(en)_2]_n

机译：基于苯-1,2,4,5-四羧酸桥联配体[Cu_2（btec）（en）_2] _n的新型3-D配位聚合物的水热合成，晶体结构和电化学性质

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A new 3-D copper(II) complex, formulated as [Cu_2(2,bbt ect(=e 1bec]n))ze( ne_e[n-1H,)2_,4_,n5-4 tetracarboxylate, and en = ethylenediamine], was hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, and single crystal X-ray diffraction. The structural analysis of 1 reveals that copper(II) connect by μ-bridging b_tec to 6form a 3-D cordination polymer, in which four carboxylates of btec show monodentate and bidentate coordination. Complex 1 was used as solid bulkmodifier to fabricate renewable carbon paste electrode (1-CPE) by direct mixing method. The cyclic voltammogram of 1 -CPE displayed one-electron quasi-reversible redox waves in potential range 300 to —300 mV due to Cu(II)/Cu(I). Moreover, 1-CPE showed electrocatalytic activity toward the reduction of nitrite.

机译：一种新的3-D铜（II）配合物，配制成[Cu_2（2，bbt ect（= e 1bec] n））ze（ne_e [n-1H，）2_，4_，n5-4四羧酸盐，en =乙二胺进行水热合成，并通过元素分析，红外光谱，热重分析和单晶X射线衍射对其结构进行表征。 1的结构分析表明，铜（II）通过μ桥接b_tec连接到6以形成3-D绳索化聚合物，其中btec的四个羧酸盐显示出单齿和双齿配位。配合物1用作固体填充剂，通过直接混合法制备可再生碳糊电极（1-CPE）。 1-CPE的循环伏安图显示，由于Cu（II）/ Cu（I），单电子准可逆氧化还原波的电势范围为300至-300 mV。而且，1-CPE显示出对亚硝酸盐还原的电催化活性。

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《Journal of Coordination Chemistry》 |2010年第8期|共9页
作者
HONGYAN LIN; HAILIANG HU; XIULI WANG; BAO MU; JIN LI;
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正文语种 eng
中图分类无机化学;
关键词
Copper complex; Hydrothermal synthesis; Crystal structure; Electrochemical property;

机译：铜配合物水热合成晶体结构电化学性能;

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1. Hydrothermal synthesis, crystal structure, and electrochemical property of a new 3-D coordination polymer based on benzene-1,2,4,5-tetracarboxylate bridging ligand: [Cu_2(btec)(en)_2]_n [J] . HONGYAN LIN, HAILIANG HU, XIULI WANG, Journal of Coordination Chemistry . 2010,第8期

机译：基于苯-1,2,4,5-四羧酸桥联配体[Cu_2（btec）（en）_2] _n的新型3-D配位聚合物的水热合成，晶体结构和电化学性质
2. A novel three-dimensional Sr-II coordination polymer based on benzene-1,2,4,5-tetracarboxylate: hydrothermal synthesis, crystal structure and spectroscopic and thermal studies [J] . Trifa Chahrazed, Mokhtari Samia, Bouacida Sofiane, Acta crystallographica. Section F, Structural biology communications . 2017,第5期

机译：基于苯-1,2,4,5-四羧酸盐的新型三维SR-II配位聚合物：水热合成，晶体结构和光谱和热研究
3. A novel three-dimensional SrII coordination polymer based on benzene-1,2,4,5-tetracarboxylate: hydrothermal synthesis, crystal structure and spectroscopic and thermal studies [J] . Chahrazed Trifa, Samia Mokhtari, Sofiane Bouacida, Acta crystallographica. Section C, Structural chemistry. . 2017,第5期

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8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 63. Synthesis of Eight-Membered-Ring Metallacycles: X-Ray Crystal Structures [R] . Elliott, G. P., Howard, J. A., Mise, T., 1987

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。第63部分。八元环金属环的合成：X射线晶体结构

Hydrothermal synthesis, crystal structure, and electrochemical property of a new 3-D coordination polymer based on benzene-1,2,4,5-tetracarboxylate bridging ligand: [Cu_2(btec)(en)_2]_n

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