Sonochemical syntheses and characterization of new nanorod crystals of mercury(II) metal organic polymer generated from polyimine ligands

MOHAMMAD YASER MASOOMI; GHODRAT MAHMOUDI; ALI MORSALI

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Sonochemical syntheses and characterization of new nanorod crystals of mercury(II) metal organic polymer generated from polyimine ligands

机译：聚亚胺配体产生的新型汞（II）金属有机聚合物纳米棒晶体的声化学合成和表征

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Nanorod crystals of two new mercury(II) [Hg(II)] coordination polymers, [Hg(4-bpdh)Br_2]_n (1) and [Hg(3-bpdh)Br_2]_n (2) {4-bpdh 2,5-bis(4-pyridyI)-3,4-diaza-2,4-hexadiene and 3-bpdh - 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene}, were prepared from the reaction of Hg(II) bromide with 4-bpdh and 3-bpdh by a sonochemical method. The nanorod crystals of 1 and 2 were characterized by scanning electron microscopy, X-ray powder diffraction, and IR spectroscopy. Compounds 1 and 2 were structurally characterized by single-crystal X-ray diffraction. The thermal stabilities of 1 and 2 were studied by thermal gravimetric and differential thermal analyses, which revealed that nanostructures of 1 and 2 are somewhat less stable than their bulk materials.

机译：两种新型汞（II）[Hg（II）]配位聚合物[Hg（4-bpdh）Br_2] _n（1）和[Hg（3-bpdh）Br_2] _n（2）{4-bpdh 2 ，5-双（4-吡啶I）-3,4-二氮杂-2,4-己二烯和3-bpdh-2,5-双（3-吡啶基）-3,4-二氮杂2,4-己二烯}，通过声化学方法由溴化汞（II）与4-bpdh和3-bpdh的反应制备。通过扫描电子显微镜，X射线粉末衍射和IR光谱表征1和2的纳米棒晶体。化合物1和2通过单晶X射线衍射进行结构表征。通过热重分析和差热分析研究了1和2的热稳定性，结果表明1和2的纳米结构比其本体材料的稳定性差一些。

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《Journal of Coordination Chemistry》 |2010年第7期|共8页
作者
MOHAMMAD YASER MASOOMI; GHODRAT MAHMOUDI; ALI MORSALI;
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正文语种 eng
中图分类无机化学;
关键词
Sonochemical; Nanoparticle; Mercury(II); 2; 5-Bis(4-pyridyI)-3; 4-diaza-2; 4- hexadiene; 2; 5-Bis(3-pyridyl)-3; 4-diaza-2; 4-hexadiene;

机译：声化学;纳米颗粒;汞（II）;2;5-双（4-吡啶I）-3;4-重氮-2;4-己二烯;2;5-双（3-吡啶基）-3;4-重氮-2;4-己二烯;

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专利

1. Sonochemical syntheses and characterization of new nanorod crystals of mercury(II) metal organic polymer generated from polyimine ligands [J] . MOHAMMAD YASER MASOOMI, GHODRAT MAHMOUDI, ALI MORSALI Journal of Coordination Chemistry . 2010,第7期

机译：聚亚胺配体产生的新型汞（II）金属有机聚合物纳米棒晶体的声化学合成和表征
2. Metal-organic supramolecular assemblies generated from bismuth(III) bromide and polyimine ligands [J] . Soltanzadeh N, Morsah A Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第4期

机译：由溴化铋（III）和聚亚胺配体生成的金属有机超分子组装体
3. Syntheses, Characterization, and Crystal Structures of a Dinuclear Complex and Coordination Polymer of Mercury(II) with Schiff Base Ligands containing N_3 and N_4 Donors [J] . Marjan Abedi, Ali Akbar Khandar, Masoumeh Servati Gargari, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第11期

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4. Syntheses and characterization of a new nano-structure lead (II) coordination polymer by sonochemical method [C] . 2010 International Conference on Enabling Science and Nanotechnology . 2010

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5. Syntheses and characterization of homo- and heterometallic tert-butoxides/cyclopentadienides of group 4/14 metals and mixed ligand (tert-butoxides/cyclopentadienides) coordination polymers of group 1/14 metals [D] . Njua, Edmond Yong 2012

机译：4/14族金属的均金属和杂金属叔丁氧化物/环戊二烯与1/14族金属的混合配体（叔丁氧化物/环戊二烯）配位聚合物的合成与表征
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机译：含有二氯甲基镓（III）（一种无机聚合物）的晶体和分子结构的mesitylgallium Chloride化合物的合成与表征

Sonochemical syntheses and characterization of new nanorod crystals of mercury(II) metal organic polymer generated from polyimine ligands

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