A cobalt(II) coordination polymer with mixed 4-(5-mercapto-1H-tetrazol-1-yl)benzoate and 4,4′-bipyridine ligands: synthesis, crystal structure, and magnetic properties

CHUN-SEN LIU; E. CAROLINA SANUDO; MIN HU; QIANG ZHANG; LIANG-QI GUO; SHAO-MING FANG

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A cobalt(II) coordination polymer with mixed 4-(5-mercapto-1H-tetrazol-1-yl)benzoate and 4,4′-bipyridine ligands: synthesis, crystal structure, and magnetic properties

机译：具有混合的4-（5-巯基-1H-四唑-1-基）苯甲酸酯和4,4'-联吡啶配体的钴（II）配位聚合物：合成，晶体结构和磁性

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A Co~(II) coordination polymer, {[Co(L)(bipy)(H_2O)_2](H_2O)_2]∞ (1), with 4-(5-mercapto1H-tetrazol-1-yl)benzoate (L) and 4,4′-bipyridine (bipy), was synthesized and structurally characterized by single-crystal X-ray diffraction analysis. Complex I has a (4,4) 2-D network structure, which is further interlinked by inter-layer O-H ··· O hydrogen-bonding interactions to form a 2-fold interpenetrated binodal (3,5)-connected 3-D hydrogen-bonded (6~3)(6~8·8~2) topology. The magnetic properties of 1 feature weak antiferromagnetic coupling.

机译：Co〜（II）配位聚合物，{[Co（L）（bipy）（H_2O）_2]（H_2O）_2]∞（1）与4-（5-巯基1H-四唑-1-基）苯甲酸酯（L ）和4,4'-联吡啶（bipy）的合成，并通过单晶X射线衍射分析对其结构进行了表征。配合物I具有（4,4）2-D网络结构，该结构通过层间OH···O氢键相互作用进一步相互连接，从而形成2倍互穿双脚架（3,5）连接的3-D氢键（6〜3）（6〜8·8〜2）拓扑。 1的磁特性具有弱的反铁磁耦合。

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《Journal of Coordination Chemistry》 |2010年第19期|共10页
作者
CHUN-SEN LIU; E. CAROLINA SANUDO; MIN HU; QIANG ZHANG; LIANG-QI GUO; SHAO-MING FANG;
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正文语种 eng
中图分类无机化学;
关键词
Co~(II) complex; 4-(5-Mercapto-1H-tetrazol-1-yl)benzoic acid; Crystal structure; 2-Fold interpenetration; Magnetic properties;

机译：Co〜（II）配合物;4-（5-巯基-1H-四唑-1-基）苯甲酸;晶体结构;2-折叠互穿;磁性;

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1. A cobalt(II) coordination polymer with mixed 4-(5-mercapto-1H-tetrazol-1-yl)benzoate and 4,4′-bipyridine ligands: synthesis, crystal structure, and magnetic properties [J] . CHUN-SEN LIU, E. CAROLINA SANUDO, MIN HU, Journal of Coordination Chemistry . 2010,第19期

机译：具有混合的4-（5-巯基-1H-四唑-1-基）苯甲酸酯和4,4'-联吡啶配体的钴（II）配位聚合物：合成，晶体结构和磁性
2. Synthesis,crystal structure and luminescent properties of a new 3D coordination polymer constructed by Cd(II)with 4,4'-oxybis(benzoate)and 4,4'-bipyridine [J] . Yi Ma, Yongke He, Litian Zhang Structural Chemistry . 2007,第6期

机译：Cd（II）与4,4'-氧双（苯甲酸酯）和4,4'-联吡啶构成的新型3D配位聚合物的合成，晶体结构和发光性能
3. Coordination polymer changing its magnetic properties and colour by thermal decomposition: synthesis, structure and properties of new thiocyanato iron(II) coordination polymers based on 4,4 '-bipyridine as ligand [J] . Wriedt M, Sellmer S, Nather C Dalton transactions: An international journal of inorganic chemistry . 2009,第38期

机译：通过热分解改变其磁性和颜色的配位聚合物：以4,4'-联吡啶为配体的新型硫氰酸根合铁（II）配位聚合物的合成，结构和性能
4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(III) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He, International Conference on Advanced Engineering Materials and Technology . 2013

机译：用2,2'-硼烷-4,4'-二羧酸的两种新三维Ce（III）配位聚合物的合成，结构和性质
5. Investigation of magnetic properties in the case of three families of 1-dimensional magnets: M(II)A(4,4'-bipyridine); M = iron, cobalt, nickel, copper; A = chloride, nitrogen, (ox). [D] . Danilovic, Dusan S. 2010

机译：研究三族一维磁体的磁性能：M（II）A（4,4'-bipyridine）; M =铁，钴，镍，铜； A =氯，氮（ox）。
6. An Oxalate-Bridged Copper(II) Complex Combining Monodentate Benzoate 22′-bipyridine and Aqua Ligands: Synthesis Crystal Structure and Investigation of Magnetic Properties [O] . Francielli Sousa Santana, Matteo Briganti, Rafael A. Allão Cassaro, 2020

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机译：6-氟硝基的第一配位化合物：含有混合配体6-氟硝基酸盐的一维镍（II）配位聚合物的晶体结构和4,4'-硼啶

A cobalt(II) coordination polymer with mixed 4-(5-mercapto-1H-tetrazol-1-yl)benzoate and 4,4′-bipyridine ligands: synthesis, crystal structure, and magnetic properties

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