Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition

SUBRATA JANA; SHOUVIK CHATTOPADHYAY

首页> 外文期刊>Journal of Coordination Chemistry >Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition

【24h】

Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition

机译：混合价铜（II）-铜（I）配位聚合物{[Cu（1,2-pn）_2（μ_3-I）Cu_2（μ_2-I）_3（CH_3CN）] CH_3CN} _n的形成：原位还原环境条件下铜（II）的数量

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A mixed valence copper(II)-copper(I) coordination polymer has been synthesized starting from a copper(II) salt at ambient condition and characterized by IR and Raman spectra and single crystal X-ray diffraction. The structure of the complex consists of a 1-D infinite chain with repeating unit [Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] and a free CH_3CN, where 1,2-pn = 1,2-diamino-1-propene. The complex shows a very short copper(I)-copper(I) distance (2.412 A).

机译：在环境条件下，从铜（II）盐开始合成了混合价铜（II）-铜（I）配位聚合物，并通过IR和拉曼光谱以及单晶X射线衍射对其进行了表征。配合物的结构由一维无限链和重复单元[Cu（1,2-pn）_2（μ_3-I）Cu_2（μ_2-I）_3（CH_3CN）]和自由的CH_3CN组成，其中， 2-pn ＝ 1，2-二氨基-1-丙烯。该配合物显示出非常短的铜（I）-铜（I）距离（2.412 A）。

著录项

来源
《Journal of Coordination Chemistry》 |2013年第22期|共9页
作者
SUBRATA JANA; SHOUVIK CHATTOPADHYAY;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Copper(II); Copper(I); μ_3-I; Crystal structure; Coordination polymer;

机译：铜（II）;铜（I）;μ_3-I;晶体结构;配位聚合物;

相似文献

外文文献
中文文献
专利

1. Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition [J] . SUBRATA JANA, SHOUVIK CHATTOPADHYAY Journal of Coordination Chemistry . 2013,第21a22期

机译：混合价铜（II）-铜（I）配位聚合物{[Cu（1,2-pn）_2（μ_3-I）Cu_2（μ_2-I）_3（CH_3CN）] CH_3CN} _n的形成：原位还原环境条件下铜（II）的数量
2. A New Porous 3-D Framework Constructured From Fivefold Parallel Interpenetration of 2-D (6,3) Nets: A Mixed-Valence Copper(I,II) Coordination Polymer [Cu_2~ICu~(II)(4,4-bpy)_2(pydc)_2](centre dot)4H_2O [J] . Xian-Ming Zhang, Xiao-Ming Chen European journal of inorganic chemistry . 2003,第3期

机译：由2-D（6,3）网五重平行互穿构造的新型多孔3-D框架：混合价铜（I，II）配位聚合物[Cu_2〜ICu〜（II）（4,4-bpy） _2（pydc）_2]（中心点）4H_2O
3. In situ solid state formation of copper(I) coordination polymers by thermal reduction of copper(II) precursor compounds: Structure and reactivity of [Cu(NCS)_2(pyrimidine)_2]_n [J] . Wriedt M., N?ther C. Dalton transactions: An international journal of inorganic chemistry . 2009,第46期

机译：通过热还原铜（II）前体化合物原位固态形成铜（I）配位聚合物：[Cu（NCS）_2（嘧啶）_2] _n的结构和反应性
4. Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer Cu(II)C_(16) H_(18) N_4O_4S_n [C] . LI Jia-gui, ZHU Wan-ren, DING Shu-hong, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：新型铜（II）配位聚合物的合成和晶体结构Cu（II）C_（16）H_（18）N_4O_4S _N
5. I. Heterogeneous cross-coupling reactions catalyzed by nickel-in-charcoal and copper-in-charcoal. II. Asymmetric 1,2/1,4-reductions catalyzed by copper hydride. III. Atropselective synthesis of the biaryl A-B ring system of vancomycin utilizing an internally tethered, nonracemic ligand. [D] . Lee, Ching-Tien. 2009

机译：I.炭中镍和炭中铜催化的非均相交叉偶联反应。二。氢化铜催化的不对称1,2 / 1,4-还原反应。三，利用内部束缚的非外消旋配体进行万古霉素联芳基A-B环系统的选择性催化合成。
6. Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex: {Bis(ethylenediamine) Copper (II) Bisdiiodocuprate (I)} [O] . Lida Fotouhi, Saeed Dehghanpour, Majid M. Heravi, 2007

机译：新型混合价铜（I）-铜（II）配合物的电化学合成和结构表征：{双（乙二胺）铜（II）双二碘多丁酸酯（I）}
7. Photocatalytic CC Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II) [O] . -1

机译：用混合价铜（I）/铜（I）的光催化CC从二氧化碳上减少氧化铜（I）/铜（II）
8. The Interaction of Hydrazine with Copper(II) Chloride in Acidic Solutions. The Formation, Spectral and Magnetic Properties, and Structures of Copper(II), Copper(I), and Mixed Valence Species. [R] . Brown, D. B., Donner, J. A., Hall, J. W., 1979

机译：肼与氯化铜（II）在酸性溶液中的相互作用。铜（II），铜（I）和混合价物种的形成，光谱和磁性以及结构。

Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition

摘要

著录项

相似文献

相关主题

期刊订阅