EQCM and EIS studies of Zn_(aq)~(2+) + 2e - <-> Zn~0 electrochemical reaction in moderated acid medium

D. Gimenez-Romero; J. J. Garcia-Jareno; F. Vicente

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EQCM and EIS studies of Zn_(aq)~(2+) + 2e - <-> Zn~0 electrochemical reaction in moderated acid medium

机译：Zn_（aq）〜（2+）+ 2e-<-> Zn〜0在中等酸性介质中的电化学反应的EQCM和EIS研究

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The zinc electrodissolution and electrodeposition have been studied by means of electrochemical quartz crystal microbalance and electrochemical impedance spectroscopy. Relevant information on the mechanism of these electrochemical processes is provided by the analysis of experimental data. The zinc electrodeposition takes place with an important participation of hydrogen ions while the zinc electrodissolution occurs, in these experimental conditions, by a mechanism in two steps. Besides, it is proved that the presence of molecular oxygen in the solution contributes to the formation of a passive layer on the metallic zinc deposit.

机译：通过电化学石英晶体微量天平和电化学阻抗谱研究了锌的电溶解和电沉积。通过实验数据的分析，提供了有关这些电化学过程机理的相关信息。在这些实验条件下，锌的电沉积是在氢离子的重要参与下发生的，而锌的电溶解则是通过两步机理进行的。此外，已证明溶液中分子氧的存在有助于在金属锌沉积物上形成钝化层。

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《Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry》 |2003年第0期|共9页
作者
D. Gimenez-Romero; J. J. Garcia-Jareno; F. Vicente;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
EQCM; zinc passivation; zinc electrodeposition; zinc electrodissolution; EIS simulation; kinetic constants values;

机译：EQCM;锌钝化;锌电沉积;锌电溶解;EIS模拟;动力学常数;

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1. EQCM and EIS studies of Zn_(aq)~(2+) + 2e - <-> Zn~0 electrochemical reaction in moderated acid medium [J] . D. Gimenez-Romero, J. J. Garcia-Jareno, F. Vicente Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2003,第0期

机译：Zn_（aq）〜（2+）+ 2e-<-> Zn〜0在中等酸性介质中的电化学反应的EQCM和EIS研究
2. Studies on the synthesis and characterization of Zn_(1-x)Cd _xS and Zn_(1-x)Cd_xS:Mn~(2+) semiconductor quantum dots [J] . Sakthi Sudar Saravanan R., Pukazhselvan D., Mahadevan C.K. Philosophical magazine: structure and properties of condensed matter . 2011,第1a3期

机译：Zn_（1-x）Cd_xS和Zn_（1-x）Cd_xS：Mn〜（2+）半导体量子点的合成与表征
3. Kinetics of solid state reactions Co~(2+), Cu~(2+) and Zn~(2+) basic carbonates with some aliphatic acids [J] . M. A. Moustafa, Z. A. Omran, W. A. A. Bayoumy, Journal of thermal analysis and calorimetry . 2001,第2期

机译：Co〜（2 +），Cu〜（2+）和Zn〜（2+）碱性碳酸盐与某些脂肪酸的固相反应动力学
4. Comparison of Gain-switched Operated Cr~(2+) and Fe~(2+) Ions Co-doped Zn_(1-x)Mn_xSe and Zn_(1-x)Mg_xSe (x ≈ 0.3) Lasers in Mid-IR under Different Excitation Wavelengths [C] . Adam Riha, Helena Jelinkova, Maxim E. Doroshenko, Conference on High Power Lasers and Applications . 2021

机译：增益切换操作CR〜（2+）和Fe〜（2+）离子的比较掺杂Zn_（1-x）mn_xse和zn_（1-x）mg_xse（x≈0.3）在中外IR下的激光激发波长
5. Electrochemical Quartz Crystal Microbalance (EQCM) studies of electrocatalytic reactions. [D] . Zhang, Meijie. 1994

机译：电化学石英晶体微天平（EQCM）对电催化反应的研究。
6. Antigenicity and conformational analysis of the Zn(2+)-binding sites of two Zn(2+)-metalloproteases: Leishmania gp63 and mammalian endopeptidase-24.11. [O] . K P Soteriadou, A K Tzinia, E Panou-Pamonis, 1996

机译：抗原性和构象分析的两个锌（2 +）-金属蛋白酶：利什曼原虫gp63和哺乳动物内肽酶-24.11的锌（2+）结合位点。
7. Raman spectroscopy study of internal dynamics in Pb(Zn_{1/3}Nb_{2/3})O_{3} and 95.55%Pb(Zn_{1/3}Nb_{2/3})O_{3}-4.5%PbTiO_{3} crystals [O] . Svitelskiy, O., La-Orauttapong, D., Toulouse, J., 2004

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8. Electrochemical oxidation of organic waste and activated graphite by Ag(sup 2+) in nitric acid: a literature study [R] . Van Alsenoy, V. , Rahier, A. 1996

机译：ag（sup 2+）在硝酸中对有机废物和活性石墨的电化学氧化：文献研究

EQCM and EIS studies of Zn_(aq)~(2+) + 2e - <-> Zn~0 electrochemical reaction in moderated acid medium

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