CHRONOAMPEROMETRY FOR THE DETERMINATION OF METALLIC INTERDIFFUSION COEFFICIENTS - RAPID TRANSPORT PROCESSES IN THE FIRST ATOMIC LAYERS

Lantelme F.; Chemla M.

首页> 外文期刊>Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry >CHRONOAMPEROMETRY FOR THE DETERMINATION OF METALLIC INTERDIFFUSION COEFFICIENTS - RAPID TRANSPORT PROCESSES IN THE FIRST ATOMIC LAYERS

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CHRONOAMPEROMETRY FOR THE DETERMINATION OF METALLIC INTERDIFFUSION COEFFICIENTS - RAPID TRANSPORT PROCESSES IN THE FIRST ATOMIC LAYERS

机译：计时光度法测定金属互扩散系数-第一原子层中的快速传输过程。

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The potential step technique was used to study the interdiffusion in the solid state at high temperature using a molten electrolyte. The method was applied to several binary metal systems and proved to be efficient for the determination of the interdiffusion coefficient D as a function of the temperature and composition of the generated alloys. The electrochemical response at short times showed a net departure from the usual diffusion laws and could be interpreted in terms of a very fast transport in the initial layers of the metal interface. Analysis of the transients was carried out by digital simulation in order to take into account the dependence of D on the concentration and distance. [References: 15]

机译：电位阶跃技术用于研究在高温下使用熔融电解质的固态相互扩散。该方法已应用于几种二元金属系统，并被证明对于确定互扩散系数D是温度和所生成合金成分的函数是有效的。短时间的电化学反应显示出与常规扩散定律的净偏离，可以用在金属界面初始层中非常快速的传输来解释。通过数字仿真对瞬态进行分析，以考虑D对浓度和距离的依赖性。 [参考：15]

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《Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry》 |1995年第2期|共7页
作者
Lantelme F.; Chemla M.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;分析化学;
关键词
Chronoamperometry; Interdiffusion coefficient; Binary metal system; Alloys;

机译：计时安培;互扩散系数;二元金属体系;合金;

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1. CHRONOAMPEROMETRY FOR THE DETERMINATION OF METALLIC INTERDIFFUSION COEFFICIENTS - RAPID TRANSPORT PROCESSES IN THE FIRST ATOMIC LAYERS [J] . Lantelme F., Chemla M. Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1995,第1a2期

机译：计时光度法测定金属互扩散系数-第一原子层中的快速传输过程。
2. Determination of Average Ternary Interdiffusion Coefficients UsingMoments of Interdiffusion Flux and Concentration Profiles [J] . N. Garimella, H.J. Choi, Y.H. Sohn Diffusion and Defect Data. Solid State Data, Part A. Defect and Diffusion Forum . 2010,第Pta2期

机译：利用互扩散通量矩和浓度分布图确定平均三元互扩散系数
3. X-ray reflectivity measurement of interdiffusion in metallic multilayers during rapid heating [J] . Liu J. P., Kirchhoff J., Zhou L., Journal of synchrotron radiation . 2017,第4期

机译：快速加热期间金属多层间隙X射线反射率测量
4. Determination of the Interdiffusion Coefficients of Liquid Zn and Sn using Ta/Zn-Sn/Si Trilayers [C] . J.H. Zhao, J.H. Zhao, W.K. Wang International conference on diffusion in materials . 2001

机译：使用TA / Zn-Sn / Si三层仪的液体Zn和Sn的相互扩散系数的测定
5. METHODOLOGY FOR QUANTITATING RAPID TRANSPORT PROCESSES IN MONOLAYER CELL CULTURES. [D] . FIESE, EUGENE FRED. 1980

机译：定量单层细胞培养中快速运输过程的方法学。
6. X-ray reflectivity measurement of interdiffusion in metallic multilayers during rapid heating [O] . J. P. Liu, J. Kirchhoff, L. Zhou, -1

机译：快速加热过程中金属多层互扩散的X射线反射率测量
7. X-ray reflectivity measurement of interdiffusion in metallic multilayers during rapid heating [O] . Liu, J. P., Kirchhoff, J., Zhou, L., 2017

机译：快速加热过程中金属多层互扩散的X射线反射率测量
8. Amorphization by Interdiffusion in Metallic Multilayers [R] . Hollanders, M. A. 1990

机译：金属多层膜中相互扩散的非晶化

CHRONOAMPEROMETRY FOR THE DETERMINATION OF METALLIC INTERDIFFUSION COEFFICIENTS - RAPID TRANSPORT PROCESSES IN THE FIRST ATOMIC LAYERS

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