The formulation and modeling of the anodic dissolution of zinc through adsorbed intermediates

Lang GG; Horanyi G

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The formulation and modeling of the anodic dissolution of zinc through adsorbed intermediates

机译：锌通过吸附中间体的阳极溶解的公式和模型

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Dissolution mechanisms suggested for Zn have been discussed. It has been shown that the anions adsorbed on the metal or metal hydroxide surfaces play an important role in the dissolution process, therefore involvement of anions in the charge and mass balance cannot be neglected. An attempt has been made to demonstrate that without taking into account the real meaning of charge transfer processes, the application of the suggested mechanism and the relevant kinetic equations may lead to serious problems in the interpretation of the experimental results. (C) 2005 Elsevier B.V. All rights reserved.

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《Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry》 |2005年第1期|共7页
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Lang GG; Horanyi G;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
zinc dissolution mechanism; kinetics; EQCM; EIS; ion adsorption; QUARTZ-CRYSTAL MICROBALANCE; CHLORIDE ELECTROLYTES; REDOX TRANSFORMATIONS; IMPEDANCE FUNCTION; EIS; SURFACE; ELECTRODEPOSITION; ADSORPTION; PLATINUM; KINETICS;

机译：锌的溶解机理;动力学;EQCM;EIS;离子吸附;石英晶体微离子;氯化物电解质;氧化还原转变;阻抗函数;EIS;表面;电沉积;吸附;铂;动力学;

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1. Reply to "Comments on the paper entitled 'The formulation and modelling of the anodic dissolution of zinc through adsorbed intermediates"' by C. Cachet et al. [J] . Lang GG, Horanyi G Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2007,第2期

机译：C. Cachet等人对“题为“锌通过吸附中间体的阳极溶解的形成和模型”的论文的评论”的答复。
2. The anodic dissolution of zinc and zinc alloys in alkaline solution. II. Al and Zn partial dissolution from 5% Al-Zn coatings [J] . T. N. Vu, M. Mokaddem, P. Volovitch, Electrochimica Acta . 2012,第Null期

机译：锌和锌合金在碱性溶液中的阳极溶解。二。 5％的Al-Zn涂层中的Al和Zn部分溶解
3. Tracing the influence of small additions of antimony to zinc on the hydrogen evolution and anodic dissolution processes of zinc as anodes for alkaline batteries application [J] . El-Sayed Abd El-Rahman, Shilkamy Hoda A. El-Shafy, Elrouby Mahmoud International journal of hydrogen energy . 2021,第61期

机译：追踪锌氮锑锑对锌氢进化和阳极溶解过程的影响，作为碱性电池应用的阳极
4. (WALSIMBook)ANODIC DISSOLUTION RATES OF PLATINIM-ZINC AND RHODIUM-ZINC COMPOUNDS IN HYDROCHLORIC ACID [C] . H. Sasaki, M. Miyake, M. Maeda Conference on Metallurgists . 2008

机译：（Walsimbook）盐酸中铂 - 锌和铑 - 锌化合物的阳极溶出速率
5. Behaviour of the adsorbed chloride intermediate in electrocatalysis of anodic chlorine evolution at oxide film surfaces at platinum and ruthenium. [D] . Gu, Ping. 1990

机译：在铂和钌的氧化膜表面上的阳极氯析出的电催化中，吸附的氯化物中间体的行为。
6. The Influence of Dimethyl Sulfoxide as Electrolyte Additive on Anodic Dissolution of Alkaline Zinc-Air Flow Battery [O] . Soraya Hosseini, Ali Abbasi, Luc-Olivier Uginet, -1

机译：二甲基亚砜作为电解质添加剂对碱性锌空气流通电池阳极溶解的影响
7. Mathematical modeling and simulation of the dissolution of zinc anodes in industrial electroplating [O] . S D Schwöbel, V Meinhold, T Mehner, 2021

机译：工业电镀锌阳极溶解的数学建模与仿真
8. Influence of Biofilms on the Anodic Dissolution of Zinc. [R] . Little, B., Wagner, P., Hart, K., 1995

机译：生物膜对锌阳极溶解的影响。

The formulation and modeling of the anodic dissolution of zinc through adsorbed intermediates

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