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首页> 外文期刊>Journal of Geophysical Research. Biogeosciences >TESTING THE DAYTIME OXIDIZING CAPACITY OF THE TROPOSPHERE - 1994 OH FIELD CAMPAIGN AT THE IZANA OBSERVATORY, TENERIFE
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TESTING THE DAYTIME OXIDIZING CAPACITY OF THE TROPOSPHERE - 1994 OH FIELD CAMPAIGN AT THE IZANA OBSERVATORY, TENERIFE

机译:测试对流层白天的氧化能力-1994年,特纳里菲州伊萨纳天文台的野外野营活动

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摘要

A field campaign was carried out during May 1994 at the Izana station, Tenerife. This campaign was part of the program Environment and Climate sponsored by the European Commission to study tile influence of European emissions on the oxidizing capacity of a clean tropospheric environment. Daytime and also nighttime measurements were made, covering the OH as well as the NO3 chemistry. This paper presents the OH measurements taken with a multipass optical absorption spectrometer (MOAS) and discusses the daytime chemistry in a statistical and therefore more preliminary way. All relevant parameters influencing the OH concentration were monitored. From the data the two main contributions to the OH production can clearly be discerned and are given by the primary production following the ozone photolysis and the O(D-1)-H2O reaction and by the catalytic reactions of NOx in the recycling process. The latter processes prove to contribute a dominant part to the OH concentration. The measurements of the nonmethane hydrocarbons (NMHC) especially of the biogenics, indicate a considerable influence of the NMHC on the absolute values of the OH concentration at Tenerife. [References: 12]
机译:1994年5月在特内里费岛伊萨纳站进行了一次野战。这项运动是欧洲委员会发起的“环境与气候”计划的一部分,目的是研究欧洲排放物对清洁对流层环境氧化能力的影响。白天和晚上都进行了测量,涵盖了OH和NO3的化学成分。本文介绍了使用多通道光吸收光谱仪(MOAS)进行的OH测量,并以统计学的方式并因此以更初步的方式讨论了日间化学反应。监测影响OH浓度的所有相关参数。从数据中可以清楚地看出对OH产生的两个主要贡献,并由臭氧光解和O(D-1)-H2O反应后的主要产物以及循环过程中NOx的催化反应给出。后面的过程证明对OH浓度起主要作用。对非甲烷碳氢化合物(NMHC)尤其是生物基因组的测量表明,NMHC对特内里费岛的OH浓度绝对值有相当大的影响。 [参考:12]

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