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首页> 外文期刊>Journal of industrial and engineering chemistry >Metachromatic behavior: Influence of the molecular weights of chitosan in thionine-sodium dodecyl sulfate system
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Metachromatic behavior: Influence of the molecular weights of chitosan in thionine-sodium dodecyl sulfate system

机译:变色行为:壳聚糖分子量在硫氨酸-十二烷基硫酸钠体系中的影响

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摘要

Chitosans having three molecular weights (4.0 x 10~4,8.0 x 10~4, and 16.0 x 10~4 Da) were isolated by an ultrasonic degradation of chitin obtained from crab shell wastes and used to determine a metachromic behavior from the effect of aggregation characteristics. The metachromatic behaviors of thionine (Th)-sodium dodecyl sulfate (SDS), Th-SDS-chitosan system were investigated by the absorption and fluorescence spectroscopy.For SDS/Th < 40, the order of decrease of fluorescence intensity in Th-SDS-chitosan system was found to be 40k > 80k > 160k of molecular weight of chitosan. In spite of adding small amount of chitosan to Th-SDS system, a reversal of metachromatic behavior in the Th-SDS-chitosan system occurs. From the measurement of the solvent effect by adding ethanol to Th-SDS-chitosan system, the order of increase of the disaggregation was determined to be 40k < 80k < 160k of molecular weights of chitosan.
机译:通过对蟹壳废物中的几丁质进行超声波降解,分离出具有三种分子量(4.0 x 10〜4、8.0 x 10〜4和16.0 x 10〜4 Da)的壳聚糖,并根据其作用确定变色行为。聚集特征。通过吸收和荧光光谱研究了亚硫氨酸(Th)-十二烷基硫酸钠(SDS),Th-SDS-壳聚糖系统的变色行为。对于SDS / Th <40,Th-SDS-S中荧光强度的降低顺序为:壳聚糖系统的分子量为40k> 80k> 160k。尽管向Th-SDS系统中添加了少量的壳聚糖,但在Th-SDS-壳聚糖系统中发生了变色行为的逆转。通过向Th-SDS-壳聚糖体系中添加乙醇来测量溶剂效果,确定了解聚增加的顺序为:壳聚糖分子量为40k <80k <160k。

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