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首页> 外文期刊>Journal of industrial and engineering chemistry >The photovoltaic efficiencies on dye sensitized solar cells assembled with nanoporous carbon/TiO2 composites
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The photovoltaic efficiencies on dye sensitized solar cells assembled with nanoporous carbon/TiO2 composites

机译:纳米多孔碳/ TiO2复合材料组装的染料敏化太阳能电池的光伏效率

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This study examined the characterization of nanoporous structured carbon/TiO2 composites and its application to dye-sensitized solar cells. TEM of nanoporous structured carbon revealed nanopore sizes of 2.0-3.0 nm with a regular hexagonal form. When nanoporous structured carbon was mixed to TiO2 particles and then was applied to DSSC, the energy conversion efficiency was enhanced considerably compared with that using only nanometer sized pure TiO2: the energy conversion efficiency of the DSSC prepared from nanoporous carbon/TiO2 composites was approximately 3.38%, compared to 2.49% using pure TiO2. We confirmed from FT-IR spectroscopy that the dye molecules were attached perfectly to the surface and more was absorbed on the nanoporous structured carbon/TiO2 composite than on the pure TiO2 particles. In impedance measurements, R3 which means the Nernstian diffusion within the electrolytes was largely decreased in a cell assembled by nanoporous carbon/TiO2 composites than that of TiO2.
机译:这项研究检查了纳米多孔结构的碳/ TiO 2复合材料的表征及其在染料敏化太阳能电池中的应用。纳米多孔结构碳的TEM显示具有规则六边形形式的2.0-3.0 nm纳米孔尺寸。与仅使用纳米级纯TiO2相比,将纳米多孔结构碳混合到TiO2颗粒中然后应用于DSSC时,能量转换效率大大提高:由纳米多孔碳/ TiO2复合材料制备的DSSC的能量转换效率约为3.38 %,而使用纯TiO2则为2.49%。我们从FT-IR光谱证实,染料分子完美地附着在表面上,并且比纯TiO2颗粒吸收更多的纳米孔结构碳/ TiO2复合材料。在阻抗测量中,在纳米多孔碳/ TiO2复合材料组装的电池中,R3意味着电解质中的能斯登扩散大大降低,而TiO2则不然。

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