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首页> 外文期刊>Journal of industrial and engineering chemistry >Effect of uni-univalent salts on the mass transfer of isobutyric acid between cumene and water
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Effect of uni-univalent salts on the mass transfer of isobutyric acid between cumene and water

机译:单价盐对异丙苯与水之间异丁酸传质的影响

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摘要

Effect of NaCl and KCl salts on single drop hydrodynamic and mass transfer of isobutyric acid from aqueous to cumene phases was studied. Drop size, extraction fraction and mass transfer coefficient were decreased as a consequence of isobutyrate ion adsorption which is quite obvious from interfacial tension variations. Both the used salts caused similar trends in variations; however, KCl was to some extent more efficient. These were while solute equilibrium distribution coefficient was shifted toward higher values. Using the combined mass transfer model, accompanied with a derived empirical correlation exhibited a nice agreement, with relative deviation values mostly within ±13.6%.
机译:研究了NaCl和KCl盐对异丁酸从水相到枯烯相的单滴流体动力学和传质的影响。异丁酸根离子的吸附降低了液滴的大小,提取率和传质系数,这从界面张力的变化来看非常明显。两种用过的盐都引起相似的变化趋势。但是,氯化钾在某种程度上更有效。这些是溶质平衡分配系数向更高的值移动的时候。使用结合的传质模型,并结合导出的经验相关性表现出很好的一致性,相对偏差值大部分在±13.6%之内。

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