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首页> 外文期刊>Journal of industrial and engineering chemistry >Comparison of the photovoltaic efficiency on DSSC for nanometer sized TiO2 using a conventional sol-gel and solvothermal methods
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Comparison of the photovoltaic efficiency on DSSC for nanometer sized TiO2 using a conventional sol-gel and solvothermal methods

机译:使用常规溶胶-凝胶法和溶剂热法比较纳米级TiO2在DSSC上的光伏效率

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摘要

When the two types of TiO2 coatings prepared by sol-gel and solvothermal methods were applied to dye-sensitized solar cell (DSSC) in this study, the energy conversion efficiency of the solvothermal-modified TiO2 was considerably higher than that on the sol-gel modified TiO2; approximately 8.51 (solvothermal) and 5.93% (sol-gel) with the N719 dye under 100mW/cm2 of simulated sunlight, respectively. These results are in agreement with an electrostatic force microscopy (EFM) study showing that the electrons were transferred rapidly to the surface of the solvothermal-modified TiO2 film, compared with that on a sol-gel modified TiO2 film. Furthermore, FT-IR analysis of the films after N719 dye adsorption showed that the solvothermal-modified TiO2 had a strong band at 500 cm~(-1), which was assigned to metal-O, due to a new Ti-0 bond between the O of COO~ and a Ti atom. This peak was considerably weaker in the sol-gel modified TiO2.
机译:在这项研究中,当通过溶胶-凝胶法和溶剂热法制备的两种类型的TiO2涂料应用于染料敏化太阳能电池(DSSC)时,溶剂热改性TiO2的能量转换效率大大高于溶胶-凝胶法改性TiO2在100mW / cm2的模拟阳光下,用N719染料分别可得到约8.51(溶剂热)和5.93%(溶胶-凝胶)。这些结果与静电力显微镜(EFM)研究一致,该研究表明,与溶胶-凝胶改性的TiO2薄膜相比,电子迅速转移到了溶剂热改性的TiO2薄膜的表面。此外,N719染料吸附后的薄膜的FT-IR分析表明,溶剂热改性的TiO2在500 cm〜(-1)处具有很强的谱带,归因于金属O,这是由于之间存在新的Ti-0键COO〜的O和Ti原子。在溶胶-凝胶改性的TiO2中,该峰明显较弱。

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