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Assessment of corrosion inhibitive behavior of 2-aminothiophenol derivatives on carbon steel in 1 M HCl

机译:在1 M HCl中评估2-氨基硫酚衍生物对碳钢的缓蚀性能

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The inhibition effect of three newly synthesized 2-aminothiophenol derivatives on the corrosion of carbon steel in 1 M HCl was investigated using electrochemical measurements and quantum chemical calculations. The experimental results suggest that these compounds are efficient corrosion inhibitors and the inhibition efficiencies increase with increasing their concentrations. The efficiencies obtained from EIS measurements were in good agreement with those obtained from the polarization measurements. Polarization measurements show that these inhibitors act as mixed-type inhibitors. The adsorption of these inhibitors was found to obey Langmuir adsorption model. The computed quantum chemical properties show good correlation with experimental inhibition efficiencies. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:使用电化学测量和量子化学计算研究了三种新合成的2-氨基硫酚衍生物对碳钢在1 M HCl中腐蚀的抑制作用。实验结果表明,这些化合物是有效的缓蚀剂,并且随着浓度的增加,缓蚀效率也随之提高。从EIS测量获得的效率与从极化测量获得的效率非常一致。极化测量表明这些抑制剂起混合型抑制剂的作用。发现这些抑制剂的吸附服从Langmuir吸附模型。计算的量子化学性质显示出与实验抑制效率的良好相关性。 (C)2014大韩工业化学工程学会。由Elsevier B.V.发布。保留所有权利。

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