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首页> 外文期刊>Journal of industrial and engineering chemistry >Oxidative dehydrogenation of butenes to butadiene over Bi-Fe-Me(Me = Ni, Co, Zn, Mn and Cu)-Mo oxide catalysts
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Oxidative dehydrogenation of butenes to butadiene over Bi-Fe-Me(Me = Ni, Co, Zn, Mn and Cu)-Mo oxide catalysts

机译：Bi-Fe-Me（Me = Ni，Co，Zn，Mn和Cu）-Mo氧化物催化剂上丁烯的氧化脱氢为丁二烯

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摘要

BiFe0.65Me0.05Mo oxide catalysts promoted with different metals (Me = Ni, Co, Zn, Mn and Cu) were prepared and the effects of the transition metal addition based on multicomponent BiFeMo oxide catalysts have been investigated for the oxidative dehydrogenation of butenes to 1,3-butadiene. It has been found that the catalytic activity of BiFe0.65Me0.05Mo oxide catalysts depends on the nature of the metals employed, varying in the order of Ni > Co > Zn > Mn > Cu. Temperature-programed re-oxidation measurements revealed that the catalytic activity of the BiFe0.65Me0.05Mo oxide catalysts was well correlated with the oxygen mobility of the catalysts. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译：制备了以不同金属（Me = Ni，Co，Zn，Mn和Cu）促进的BiFe0.65Me0.05Mo氧化物催化剂，并研究了基于多组分BiFeMo氧化物催化剂的过渡金属加成对丁烯氧化脱氢制氢的影响。 1,3-丁二烯。已经发现BiFe0.65Me0.05Mo氧化物催化剂的催化活性取决于所用金属的性质，以Ni> Co> Zn> Mn> Cu的顺序变化。程序升温再氧化测量表明，BiFe0.65Me0.05Mo氧化物催化剂的催化活性与催化剂的氧迁移率密切相关。 （C）2014大韩工业化学工程学会。由Elsevier B.V.发布。保留所有权利。

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