Amelioration of the reaction kinetics of Mg with hydrogen by reactive mechanical grinding with Ni, Fe2O3, Ti or Fe

Myoung Youp Song; Young Jun Kwak; Hye Ryoung Park

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Amelioration of the reaction kinetics of Mg with hydrogen by reactive mechanical grinding with Ni, Fe2O3, Ti or Fe

机译：通过Ni，Fe2O3，Ti或Fe的反应性机械研磨改善Mg与氢的反应动力学

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The magnesium prepared by mechanical grinding under H2 (reactive mechanical grinding) with transition elements or oxides showed relatively high hydriding and dehydriding rates when the content of additives was about 20 wt%. Ni and Fe were chosen as transition elements to be added. Ti was also selected since it was considered to increase the hydriding and dehydriding rates by forming Ti hydride. Samples Mg-14Ni-6Fe2O3, Mg-14Ni-6Ti, Mg-14Ni-3Fe2O3-3Ti, and Mg-14Ni-2Fe2O3-2Ti-2Fe were prepared by reactive mechanical grinding, and their hydrogen storage properties were examined. Among these samples, Mg-14Ni-6Ti had the highest hydriding and dehydriding rates.

机译：当添加剂的含量为约20wt％时，在H 2下用过渡元素或氧化物通过机械研磨（反应性机械研磨）制备的镁表现出相对较高的氢化和脱水速率。选择Ni和Fe作为要添加的过渡元素。还选择了Ti，因为它被认为可以通过形成Ti氢化物来提高氢化和脱水速率。通过反应机械研磨制备样品Mg-14Ni-6Fe2O3，Mg-14Ni-6Ti，Mg-14Ni-3Fe2O3-3Ti和Mg-14Ni-2Fe2O3-2Ti-2Fe，并检查其储氢性能。在这些样品中，Mg-14Ni-6Ti的氢化和脱水率最高。

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来源
《Journal of industrial and engineering chemistry》 |2011年第4期|共5页
作者
Myoung Youp Song; Young Jun Kwak; Hye Ryoung Park;
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正文语种 eng
中图分类化学工业;
关键词
H2-storage properties of Mg; Addition of Ni; Fe2O3; Ti; or Fe; Reactive mechanical grinding; Mg2Ni formation; Mg(OH)2 formation;

机译：镁的储氢特性;添加镍;铁离子;钛或铁;反应性机械研磨;镁镍形成;镁（OH）2形成;

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1. Amelioration of the reaction kinetics of Mg with hydrogen by reactive mechanical grinding with Ni, Fe2O3, Ti or Fe [J] . Myoung Youp Song, Young Jun Kwak, Hye Ryoung Park Journal of industrial and engineering chemistry . 2011,第4期

机译：通过Ni，Fe2O3，Ti或Fe的反应性机械研磨改善Mg与氢的反应动力学
2. Amelioration of the hydriding and dehydriding kinetics of Mg by reactive mechanical grinding with Ni and Fe2O3 purchased and prepared by spray conversion [J] . MyoungYoup Song, SungHwan Baek, HyeRyoung Park Journal of industrial and engineering chemistry . 2010,第5期

机译：通过购买和喷涂转化制备的Ni和Fe2O3进行反应性机械研磨，改善Mg的氢化和脱水动力学
3. Hydrogenation Kinetics and Physical Characteristics of Ni, Ti, and Fe_2O_3-Added Mg by Reactive Mechanical Grinding [J] . Young Jun Kwak, Sung Nam Kwon, Hye Kyoung Park Journal of Korean Institute of Metal and Materials . 2014,第10期

机译：Ni，Ti和Fe_2O_3-添加镁的反应机械研磨加氢动力学及物理特性
4. Amelioration of the Hydrogen Storage Properties of Mg by the Addition of TiCl_3, VCl_3, NbF_5, or TaF_5 via Reactive Mechanical Grinding [C] . Seong Ho Lee, Young Jun Kwak, Hye Ryoung Park, World energy conference . 2014

机译：通过反应性机械研磨添加TiCl_3，VCl_3，NbF_5或TaF_5改善Mg的储氢性能
5. Hydrogenation of F-Nitrobenzene to F-Aminophenol under Kinetics and Mass Transfer Limited Regimes: Reaction Kinetics, Mass Transfer Effects and Reaction Pathway. [D] . Kedia, Sandeep. 2015

机译：在动力学和传质受限的条件下，将F-硝基苯加氢为F-氨基苯酚：反应动力学，传质效果和反应途径。
6. Magnetic Fe2O3–SiO2–MeO2–Pt (Me = Ti Sn Ce) as Catalysts for the Selective Hydrogenation of Cinnamaldehyde. Effect of the Nature of the Metal Oxide [O] . Robinson Dinamarca, Rodrigo Espinoza-González, Cristian H. Campos, 2019

机译：磁性Fe2O3-SiO2-MeO2-Pt（Me = TiSnCe）作为肉桂醛选择性加氢的催化剂。金属氧化物性质的影响
7. Mechanical alloys Mg-Me (Me: Ti, Fe, Ni, Al) Mg-Me1-Me2(Ме1:Al, Me2: Ti, Fe, Ni) with low resistance and improved kinetics of hydrogenation/dehydrogenation for hydrogen storage applications [O] . O. Ershova, V. Dobrovolsky, Y. Solonin 2018

机译：机械合金Mg-Me（Me：Ti，Fe，Ni，Al）＆Mg-Me1-Me2（Ме1：Al，Me2：Ti，Fe，Ni），具有低电阻和改善氢气储氢脱氢的动力学

Amelioration of the reaction kinetics of Mg with hydrogen by reactive mechanical grinding with Ni, Fe2O3, Ti or Fe

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