首页> 外文期刊>Journal of mass spectrometry: JMS >Endogenous lipase catalyzed transesterification of olive oil fats. the formation of isomeric and oligomeric triacyleglycerols
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Endogenous lipase catalyzed transesterification of olive oil fats. the formation of isomeric and oligomeric triacyleglycerols

机译:内源性脂肪酶催化橄榄油脂肪的酯交换反应。异构和低聚三酰基甘油的形成

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摘要

The role of lipase to catalyze hydrolysis and transesterification of triacylglycerols (TAGs) was evaluated in model systems as well as in virgin olive oil. Tandem mass spectrometry was applied in the identification of modified TAGs, ionized by electrospray, formed during the incubation of selected TAGs with mono and di carboxylic acids. The oligomerization of TAGs was observed in authentic olive oil samples and verified in model systems under catalysis exerted by lipase, whose presence in olive oil was already documented. The hydrolytic pathways taken under enzymatic treatment is balanced by the formation of TAG oligomers that should not alter the nutritional value of the aliment.
机译:在模型系统以及纯橄榄油中评估了脂肪酶在催化三酰基甘油(TAGs)水解和酯交换中的作用。串联质谱用于鉴定修饰的TAG,这些TAG是在单TAG和二元羧酸与所选TAG孵育期间通过电喷雾电离的。在真实的橄榄油样品中观察到TAGs的寡聚化,并在脂肪酶催化下的模型系统中得到验证,脂肪酶在橄榄油中的存在已被证明。在酶处理下采取的水解途径与TAG寡聚物的形成相平衡,该寡聚物不应改变饮食的营养价值。

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