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Effects of oxygen partial pressure control on the microstructure and PTCR properties of Ho doped BaTiO3

机译:氧分压控制对掺Ho的BaTiO3显微组织和PTCR性能的影响

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Effects of oxygen partial pressure (P-O2) control on the electrical properties and microstructural development of (Ba1-xHox)(0.997)TiO3 were studied. An oxidation condition (P-O2 similar to 1.0 atm) was maintained during the heating process, and then the specimen was sintered in a reducing atmosphere (P-O2 < 10(-9) atm) at 1350 degrees C, followed by the annealing process at 1000 degrees C and P-O2 = 1 atm. The switching temperature (T-S) from the oxidation atmosphere to the reducing condition was changed from 1100 to 1350 degrees C. A significant decrease in the room-temperature resisitivity (rho(25)) was observed as T-S was increased. The temperature coefficient of resistance (TCR) was independent of the change in T-S, and closed pores decreased with increasing T-S.
机译:研究了氧分压(P-O2)控制对(Ba1-xHox)(0.997)TiO3电学性质和微结构发展的影响。在加热过程中保持氧化条件(P-O2类似于1.0 atm),然后在还原气氛(P-O2 <10(-9)atm)中于1350摄氏度下烧结样品,然后进行退火在1000摄氏度和P-O2 = 1 atm的条件下进行处理。从氧化气氛到还原条件的转换温度(T-S)从1100变为1350℃。随着T-S的增加,观察到室温电阻率(rho(25))显着降低。电阻温度系数(TCR)与T-S的变化无关,并且闭合孔随着T-S的增加而减小。

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