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首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >Preparation, characterization and separation performances of novel dual modified PU membranes with carbon fiber filling
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Preparation, characterization and separation performances of novel dual modified PU membranes with carbon fiber filling

机译:新型碳纤维填充双改性聚氨酯膜的制备,表征和分离性能

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摘要

Novel dual modified PU membranes were prepared by β-cyclodextrin (CD) crosslinking and carbon fiber (CF) filling. The structures, thermal stabilities, morphologies and surface properties were characterized by FTIR, TGA, SEM, XRD and contact angle. PV performances were investigated for the mixture of phenol and water. The dual modified membranes showed not only higher permeability, but also better selectivity than PU membranes. At 80°C for the 0.5 wt% phenol aqueous solution, the total flux of PU was 6.59 kg μm m~(-2) h ~(-1), while the PU-CD-CF~(-1) and PU-CD-CF~(-2) were 8.10 kg μm m ~(-2) h~(-1) and 7.77 kg μm m~(-2) h~(-1) respectively; the separation factor of PU was 8.94, while the PU-CD-CF~(-2) and PU-CD-CF~(-1) were 39.63 and 37.55, respectively.
机译:通过β-环糊精(CD)交联和碳纤维(CF)填充制备了新型双重改性PU膜。通过FTIR,TGA,SEM,XRD和接触角表征了结构,热稳定性,形貌和表面性质。研究了苯酚和水的混合物的PV性能。与PU膜相比,双重改性膜不仅显示出更高的渗透性,而且还具有更好的选择性。对于80 wt%的苯酚水溶液,在80°C下,PU的总通量为6.59 kgμmm〜(-2)h〜(-1),而PU-CD-CF〜(-1)和PU- CD-CF〜(-2)分别为8.10 kgμmm〜(-2)h〜(-1)和7.77 kgμmm〜(-2)h〜(-1); PU的分离因子为8.94,而PU-CD-CF〜(-1)和PU-CD-CF〜(-1)分别为39.63和37.55。

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