Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine

Koc ZE; Ucan HI

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Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine

机译：铁（III）和铬（III）Salen和Saloph Schiff碱与2,4,6-三（4-硝基苯基亚氨基-4'-甲酰基苯氧基）-1,3,5-三嗪的配合物

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Four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(saloph H2) with 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine (TNPI-TRIPOD) have been synthesized and characterized by means of elemental analysis carrying out 1H-NMR., IR spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as high-spin distorted octahedral Fe(III) and Cr(III) bridged by nitro. The nitro play a role as bridges for weak anti-ferromagnetic intramolecular exchange.

机译：四个新的三核Fe（III）和Cr（III）配合物，涉及四齿Schiff碱N，N'-双（水杨基）乙二胺-（salenH2）或双（水杨基）-邻苯二胺-（水杨H2），含2,4，合成了6-三（4-硝基苯基亚氨基-4'-甲酰苯氧基）-1,3,5-三嗪（TNPI-TRIPOD），并通过进行1H-NMR的元素分析，红外光谱，热分析和磁学表征磁化率测量。配合物还可以表征为高旋转扭曲的八面体Fe（III）和Cr（III）硝基桥接。硝基起到弱反铁磁分子内交换的桥梁的作用。

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《Journal of Macromolecular Science. Pure and Applied Chemistry》 |2008年第12期|共6页
作者
Koc ZE; Ucan HI;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Schiff base; triazine; cyanuric chloride; salen; saloph; metal complexes; TRANSITION-METAL-COMPLEXES; BINUCLEAR; ACIDS;

机译：席夫碱;三嗪;氰尿酰氯;salen;saloph;金属配合物;过渡金属配合物;双核;酸;

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1. Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine [J] . Koc ZE, Ucan HI Journal of Macromolecular Science. Pure and Applied Chemistry . 2008,第12期

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Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine

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