Synthesis, structural characterization and preliminary cancer cell line results for polymers derived from reaction of titanocene dichloride and various poly(ethylene glycols)

Carraher Charles E. Jr.; Roner Michael R.; Reckleben Lisa; Black Kendra; Frank Jessica; Crichton Ryan; Russell Floyd; Moric-Johnson Alisa; Miller Lindsey

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Synthesis, structural characterization and preliminary cancer cell line results for polymers derived from reaction of titanocene dichloride and various poly(ethylene glycols)

机译：钛茂二氯化物与各种聚乙二醇反应生成的聚合物的合成，结构表征和初步癌细胞系结果

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We describe the initial synthesis of DMSO and water-soluble titanocene polyethers through reaction of the titanocene dichloride and various poly(ethylene glycols) employing commercially available reactants. Infrared, proton NMR, and MALDI MS results are consistent with the titanocene-containing polyether structure. The materials are polymeric with chain lengths ranging from 1500 to 4. They exhibit good inhibition of a variety of cancer cell lines including two pancreatic cancer cell lines.

机译：我们描述了二甲基茂钛二氯化物与各种聚（乙二醇）利用市售反应物的反应，从而初步合成了DMSO和水溶性二茂钛聚醚。红外，质子NMR和MALDI MS结果与含钛茂的聚醚结构一致。该材料是聚合的，链长范围为1500至4。它们对多种癌细胞系（包括两个胰腺癌细胞系）表现出良好的抑制作用。

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《Journal of Macromolecular Science. Pure and Applied Chemistry》 |2016年第9期|共9页
作者
Carraher Charles E. Jr.; Roner Michael R.; Reckleben Lisa; Black Kendra; Frank Jessica; Crichton Ryan; Russell Floyd; Moric-Johnson Alisa; Miller Lindsey;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Metal containing polymers; PEG polymers; titanocene-containing polymers; cancer; pancreatic cancer; water soluble polymers; MALDI MS;

机译：含金属的聚合物;PEG聚合物;并茂的聚合物;癌症;胰腺癌;水溶性聚合物;MALDI MS;

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1. Synthesis, structural characterization and preliminary cancer cell line results for polymers derived from reaction of titanocene dichloride and various poly(ethylene glycols) [J] . Carraher Charles E. Jr., Roner Michael R., Reckleben Lisa, Journal of Macromolecular Science. Pure and Applied Chemistry . 2016,第7a9期

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Synthesis, structural characterization and preliminary cancer cell line results for polymers derived from reaction of titanocene dichloride and various poly(ethylene glycols)

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