...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >Synthesis and Catalytic Activity of Polymer Supported Schiff Base Complexes of Copper(II) and Iron(III) Ions in Comparison to Unsupported Complexes
【24h】

Synthesis and Catalytic Activity of Polymer Supported Schiff Base Complexes of Copper(II) and Iron(III) Ions in Comparison to Unsupported Complexes

机译：聚合物负载的铜（II）和铁（III）离子席夫碱配合物与无载体配合物的合成及催化活性

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The polymer supported metal complexes of N,N'-bis(acetyl acetone)o-phenylene-diamine (ACPDA) Schiff base were synthesized bysuspension copolymerization of styrene and allyl chloride in the presence of divinyl benzene (DVB) as cross-linker and azobisisobutyroni-trile (AIBN) as initiator at 70 ± 0.1°C and then ACPDA Schiff base and metal ions were loaded on the resulting polymer beads. The cross-linked density in polymer beads was varied by taking different concentrations of divinyl benzene in the reaction mixture. The polymer beadswere characterized for their cross-linked density, size (ф), density (p), degree of swelling (%S w) and loading of ACPDA Schiff base andmetal ions. The polymer beads prepared with 1.5 mmol of DVB (Type III) had a sufficient amount of allyl chloride (4.90 mmol,0.367 g) and showed optimum loading for ACPDA Schiff base (1.96 mmol g -1) and metal ions. The structures of copper(II) andiron(III) ions complexes (ACPDA-M) and their loading on polymer beads (P-ACPDA-M) was characterized with spectral analysis. Thecatalytic activity of unsupported and polymer supported ACPDA Schiff base complexes of copper(II) and iron(III) ions was evaluatedby studying the rate of decomposition of hydrogen peroxide.
机译：N，N'-双（乙酰丙酮）邻苯二胺（ACPDA）Schiff碱的聚合物负载金属配合物是在二乙烯基苯（DVB）作为交联剂和偶氮二异丁腈的情况下通过苯乙烯与烯丙基氯的悬浮共聚反应合成在70±0.1°C下，以-trile（AIBN）作为引发剂，然后将ACPDA Schiff碱和金属离子负载在所得的聚合物珠上。通过在反应混合物中采用不同浓度的二乙烯基苯来改变聚合物珠粒中的交联密度。通过交联密度，尺寸（ф），密度（p），溶胀度（％S w）以及ACPDA Schiff碱和金属离子的负载量表征了聚合物珠粒。用1.5 mmol DVB（III型）制备的聚合物珠粒具有足够量的烯丙基氯（4.90 mmol，0.367 g），并显示出ACPDA Schiff碱（1.96 mmol g -1）和金属离子的最佳负载量。通过光谱分析表征了铜（II）和铁（III）离子配合物（ACPDA-M）的结构及其在聚合物珠粒上的负载（P-ACPDA-M）。通过研究过氧化氢的分解速率，评估了铜（II）和铁（III）离子的无载体和聚合物载体的ACPDA Schiff碱配合物的催化活性。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号