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首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >Processing and Properties of Nanocomposites Based on Layered Silicate and Carboxylated Nitrile Rubber
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Processing and Properties of Nanocomposites Based on Layered Silicate and Carboxylated Nitrile Rubber

机译:层状硅酸盐和羧化丁腈橡胶纳米复合材料的制备及性能

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摘要

Nanocomposites based on carboxylated nitrile rubber (XNBR) and organomodified clay were prepared under different mixing conditions. At higher mixing temperatures, a mixed intercalated/exfoliated morphology was obtained as evidenced by X-ray diffraction studies and transmission electron microscopy. A remarkable improvement of physical properties was achieved when the layered silicates were mixed at high temperatures. The presence of carboxylic group in the rubber improves the interaction and exfoliation process which can be shown by IR studies. With the increase of the organoclay loading and processing temperature, a considerable effect on dynamic properties was found during strain sweep analysis which was explained by 'Payne'-like effects. Finally, a mechanism of the layered silicate dispersion in carboxylated nitrile rubber has been proposed.
机译:在不同的混合条件下制备了基于羧基丁腈橡胶(XNBR)和有机改性粘土的纳米复合材料。在更高的混合温度下,获得了混合的插层/片状形态,这是通过X射线衍射研究和透射电子显微镜证明的。当在高温下混合层状硅酸盐时,物理性能得到了显着改善。橡胶中羧基的存在改善了相互作用和剥离过程,这可以通过红外研究证明。随着有机粘土负载量和加工温度的升高,在应变扫描分析过程中发现了对动力学性能的显着影响,这可以通过“ Payne”样效应来解释。最后,提出了层状硅酸盐分散在羧化丁腈橡胶中的机理。

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