Poly[di(2,5-dimercapto-1,3,4-thiadiazole)-metal] Complexes of Group IIB: Synthesis, Characterization and DC Electrical Conductivity

El-Shekeil AG; Saleh ABA; Al-Shujaa OM

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Poly[di(2,5-dimercapto-1,3,4-thiadiazole)-metal] Complexes of Group IIB: Synthesis, Characterization and DC Electrical Conductivity

机译：IIB组的聚[二（2,5-二巯基-1,3,4-噻二唑）-金属]配合物：合成，表征和直流电导率

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The reaction of 2,5-dimercapto-1,3,4-thiadiazole (DMT) (6.6 mmol) with zinc, cadmium and mercury chlorides (3.3 mmol) gave new polymer-metal complexes. The poly[di(2,5-dimercapto-1,3,4-thiadiazole)]-metal complexes of Zn(II), Cd(II) and Hg(II) were characterized by elemental analyses, electronic spectra, FTIR spectroscopy, thermal analyses (TGA and DTA) and X-Ray diffraction. The DC electrical conductivity variation with temperature in the range 300-500 K of the polymer-metal complexes after annealing for 24 h at 100C and after doping with 5% I2 is determined for comparison. The activation energies were calculated and the results were interpreted using the band energy model.

机译：2,5-二巯基-1,3,4-噻二唑（DMT）（6.6 mmol）与锌，镉和汞的氯化物（3.3 mmol）的反应产生了新的聚合物-金属配合物。 Zn（II），Cd（II）和Hg（II）的聚[di（2,5-dimercapto-1,3,4-thiadiazole）]-金属络合物的元素分析，电子光谱，FTIR光谱，热分析（TGA和DTA）和X射线衍射。为了比较，确定在100℃下退火24小时之后和掺杂5％I 2之后，聚合物-金属配合物在300-500K范围内的温度下的DC电导率变化。计算活化能，并使用能带模型解释结果。

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《Journal of Macromolecular Science. Pure and Applied Chemistry》 |2009年第1期|共9页
作者
El-Shekeil AG; Saleh ABA; Al-Shujaa OM;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Polydi(2; 5-dimercapto-1; 3; 4-thiadiazole)-metal complexes; 2; 5-dimercapto-1; 3; 4-thiadiazole; DC electrical conductivity; doping; thermal analysis; X-ray diffraction; activation energies;

机译：聚[二（2;5-二巯基-1;3;4-噻二唑）-金属]络合物;2;5-二巯基-1;3;4-噻二唑;直流电导率;掺杂;热分析;X射线衍射活化能;

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1. Poly[di(2,5-dimercapto-1,3,4-thiadiazole)-metal] Complexes of Group IIB: Synthesis, Characterization and DC Electrical Conductivity [J] . El-Shekeil AG, Saleh ABA, Al-Shujaa OM Journal of Macromolecular Science. Pure and Applied Chemistry . 2009,第1期

机译：IIB组的聚[二（2,5-二巯基-1,3,4-噻二唑）-金属]配合物：合成，表征和直流电导率
2. Poly[di(2, 5-dimercapto-1, 3,4-thiadiazole)-metal] Complexes of Group IIB: Synthesis, Characterization and DC Electrical Conductivity [J] . ALI G. EL-SHEKEIL, ABDUL-BASIT A. SALEH, OMAR M. AL-SHUJAA Journal of Macromolecular Science. Pure and Applied Chemistry . 2009,第1a3期

机译：IIB组的聚[二（2，5-二巯基-1，3,4-噻二唑）-金属]配合物：合成，表征和直流电导率
3. Synthesis, Spectral Characterization, Thermal Studies and DC Electrical Conductivity of Poly[di(2,5-dimercapto-1,3,4-thiadiazole)-Platinum (IV)] Complex [J] . Ali G. El-Shekeil, Omar M. Al-Shujaa Journal of Macromolecular Science. Pure and Applied Chemistry . 2007,第4a6期

机译：聚[di（2,5-dimercapto-1,3,4-thiadiazole）-Platinum（IV）]配合物的合成，光谱表征，热研究和直流电导率
4. New poly(2,5-dimercapto-1,3,4-thiadiazole) and poly(aniline) co-intercalated V_2O_5 nanocomposite materials for rechargeable lithium battery [C] . Nam-Gvu Park, Kwang Man Kim, Kwan Sun Ryu The Meeting of the Electrochemical Society . 2000

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5. METAL COMPLEXES OF 1,3,4-THIADIAZOLE DERIVATIVES. [D] . JAMES, SHARI ELAINE 1984

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8. Novel Battery Cathode Material Based on intercalation Chemistry: Redox Reactions of the 2,5-Dimercapto- 1,3,4-Thiadiazole/V2O5 Xerogel System [R] . Shouji, E. , Buttry, D. A. 1998

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Poly[di(2,5-dimercapto-1,3,4-thiadiazole)-metal] Complexes of Group IIB: Synthesis, Characterization and DC Electrical Conductivity

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