A one-step strategy for thermally and mechanically reinforced pseudo-interpenetrating poly(propylene carbonate) networks by terpolymerization of CO2, propylene oxide and pyromellitic dianhydride

Lijun Gao; Jiuying Feng

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A one-step strategy for thermally and mechanically reinforced pseudo-interpenetrating poly(propylene carbonate) networks by terpolymerization of CO2, propylene oxide and pyromellitic dianhydride

机译：通过CO2，环氧丙烷和均苯四甲酸二酐的三元聚合热和机械增强的伪互穿聚碳酸亚丙酯网络的一步策略

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We present a one-step effective synthetic strategy for excellent thermally and mechanically reinforced pseudo-interpenetrating polypropylene carbonate) networks (PIPPCNs) by CO2/propylene oxide/pyromellitic dianhydride terpolymerization. This strategy will enable PPC to be smoothly processed by heat without decomposition and to be used in a wider range of applications such as packaging, commodity and agriculture films.

机译：我们提出了一种通过CO2 /环氧丙烷/均苯四甲酸二酐三元聚合实现优异的热和机械增强的伪互穿碳酸丙二酯网络（PIPPCNs）的有效一步合成策略。这种策略将使PPC能够通过加热平稳地进行处理而不会分解，并可以在包装，商品和农业薄膜等更广泛的应用中使用。

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《Journal of Materials Chemistry, A. Materials for energy and sustainability》 |2013年第11期|共5页
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Lijun Gao; Jiuying Feng;
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1. A one-step strategy for thermally and mechanically reinforced pseudo-interpenetrating poly(propylene carbonate) networks by terpolymerization of CO2, propylene oxide and pyromellitic dianhydride [J] . Lijun Gao, Jiuying Feng Journal of Materials Chemistry, A. Materials for energy and sustainability . 2013,第11期

机译：通过CO2，环氧丙烷和均苯四甲酸二酐的三元聚合热和机械增强的伪互穿聚碳酸亚丙酯网络的一步策略
2. Terpolymerization of Benzyl Glycidyl Ether, Propylene Oxide, and CO_2 Using Binary and Bifunctional [rac-SalcyCo~(III)X] Complexes and the Thermal and Mechanical Properties of the Resultant Poly(benzyl 1,2-glycerol-co-propylene carbonate)s and Poly(1,2-glycerol-co-propylene carbonate)s [J] . Heng Zhang, Mark W. Grinstaff Journal of Applied Polymer Science . 2014,第5期

机译：使用二元和双官能[rac-SalcyCo〜（III）X]配合物对苄基缩水甘油醚，环氧丙烷和CO_2进行三元聚合，以及所得聚（1,2-苄基甘油-碳酸丙烯酯）的热力学性能和聚（1,2-甘油-碳酸亚丙酯）
3. Terpolymerization of Benzyl Glycidyl Ether, Propylene Oxide, and CO_2 Using Binary and Bifunctional [rac-SalcyCo~(III)X] Complexes and the Thermal and Mechanical Properties of the Resultant Poly(benzyl 1,2-glycerol-co-propylene carbonate)s and Poly(1,2-glycerol-co-propylene carbonate)s [J] . Heng Zhang, Mark W. Grinstaff Journal of Applied Polymer Science . 2014,第5期

机译：使用二元和双官能[rac-SalcyCo〜（III）X]配合物对苄基缩水甘油醚，环氧丙烷和CO_2进行三元聚合，以及所得聚（1,2-苄基甘油-碳酸丙烯酯）的热力学性能和聚（1,2-甘油-碳酸亚丙酯）
4. Enzymatic degradation of poly(propylene carbonate) and poly(propylene carbonate-co-ε-caprolactone) synthesized via CO_2 fixation [C] . Yongtaek Hwang, Moonhor Ree, Heesoo Kim International Conference on Carbon Dioxide Utilization . 2006

机译：聚（碳酸亚丙酯）和聚（碳酸亚丙酯-co-ε-己内酯）的酶促降解通过CO_2固定合成
5. Nisin adsorption and function at hydrophobic surfaces coated with the poly[ethylene oxide]-poly[propylene oxide]-poly[ethylene oxide] triblock surfactant Pluronic F108. [D] . Tai, Yuan-Ching. 2007

机译：乳链菌肽在涂有聚[环氧乙烷]-聚[环氧丙烷]-聚[环氧乙烷]三嵌段表面活性剂Pluronic F108的疏水表面上的吸附和功能。
6. Cross-Linked Networks in Poly(propylene carbonate)by Incorporating (Maleic Anhydride/cis-1236-TetrahydrophthalicAnhydride) Oligomer in CO2/Propylene Oxide Copolymerization:Improving and Tailoring Thermal Mechanical and Dimensional Properties [O] . Meiying Huang, Lijun Gao, Jiuying Feng, 2020

机译：聚碳酸亚丙酯中的交联网络通过掺入（顺丁烯二酸酐/顺式1236-四氢邻苯二甲酸CO2 /环氧丙烷共聚中的酸酐）低聚物：改善和定制热机械和尺寸特性
7. Concerning the Mechanism of the Ring Opening of Propylene Oxide in the Copolymerization of Propylene Oxide and Carbon Dioxide To Give Poly(propylene carbonate) [O] . -1

机译：关于环氧丙烷在环氧丙烷和二氧化碳的共聚中环氧化物的机理，得到聚（碳酸丙酯）
8. Structure-Property Relationships in Thermoplastic Elastomers IV. Dynamic Mechanical Relaxations in Poly(Dioxolane), Poly(Butyltrioxocane) and Poly(Propylene Oxide) Polyurethanes [R] . Chen, J. C., Rho, M. K. 1987

机译：热塑性弹性体中的结构 - 性质关系IV。聚（二氧戊环），聚（丁基三氧杂环己烷）和聚（环氧丙烷）聚氨酯的动态机械弛豫

A one-step strategy for thermally and mechanically reinforced pseudo-interpenetrating poly(propylene carbonate) networks by terpolymerization of CO2, propylene oxide and pyromellitic dianhydride

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