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首页> 外文期刊>Journal of Materials Chemistry, C. materials for optical and electronic devices >6,13-Dicyano pentacene-2,3:9,10-bis(dicarboximide) for solution-processed air-stable n-channel field effect transistors and complementary circuit
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6,13-Dicyano pentacene-2,3:9,10-bis(dicarboximide) for solution-processed air-stable n-channel field effect transistors and complementary circuit

机译:6,13-​​二氰基并五苯-2,3:9,10-双(二甲酰亚胺),用于溶液处理的空气稳定的n沟道场效应晶体管和互补电路

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摘要

Aromatic diimides have attracted much attention due to their unique properties and potential applications for n-channel organic field effect transistors (OFETs). In this study, N,N'-dialkyl-6,13-dicyano pentacene-2,3:9,10-bis(dicarboximide) (1) was synthesized and used in n-channel OFETs., The photophysical, electrochemical and thermal properties of 1 were investigated. The low LUMO energy level (-4.15 eV) located within the air stability window ensures air-stable n-channel operation. Solution-processed top-contact thin film transistors based on such linear aromatic dicarboximide showed typical n-channel characteristics with a high electron mobility of up to 0.08 cm~2 V~(-1) s~(-1) and a high I_(on)/I_(off) ratio of 10~6 to 10~7. The devices exhibited good air stability when exposed to air for several months. Complementary inverters based on n-type 1 and p-type TIPS-pentacene were fabricated, which showed a maximum voltage gain (-dV_(out)/dV_(in)) of 57.
机译:芳香族二酰亚胺因其独特的性能以及在n沟道有机场效应晶体管(OFET)中的潜在应用而备受关注。本研究合成了N,N'-二烷基-6,13-​​二氰基并五苯-2,3:9,10-双(二邻苯二甲酰亚胺)(1),并用于n通道OFETs中。研究了1的性质。位于空气稳定窗口内的低LUMO能级(-4.15 eV)确保空气稳定的n通道运行。基于这种线性芳族二羧酰亚胺的溶液处理的顶部接触薄膜晶体管表现出典型的n沟道特性,具有高达0.08 cm〜2 V〜(-1)s〜(-1)的高电子迁移率和高I_( on)/ I_(off)比率​​为10〜6到10〜7。暴露于空气中数月后,这些装置表现出良好的空气稳定性。制造了基于n型1和p型TIPS-并五苯的互补逆变器,其最大电压增益(-dV_(out)/ dV_(in))为57。

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