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首页> 外文期刊>Journal of Materials Chemistry, C. materials for optical and electronic devices >Gas-phase anion exchange towards ZnO/ZnSe heterostructures with intensive visible light emission
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Gas-phase anion exchange towards ZnO/ZnSe heterostructures with intensive visible light emission

机译:气相阴离子交换向可见光强发射的ZnO / ZnSe异质结构

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Gas-phase anion exchange favors the formation of highly crystalline and metastable nanostructures which may possess superior properties, In the present work, we employed gas-phase anion exchange to convert ZnO nanorods into ZnSe nanostructures. We found that the thick ZnO nanorods transformed into a ZnO/ ZnSe core/shell structure with a zinc blende ZnSe shell via nucteation and growth of ZnSe nanoparticles, while the thin ones could directly template the growth of pure WZ-ZnSe nanorods. The ZnO/ZnSe heterostructure shows intensive green emission, which arises from the V_(Zn)-related defect complexes in the ZnO core.
机译:气相阴离子交换有利于形成具有较高性能的高度结晶和亚稳的纳米结构。在本工作中,我们采用气相阴离子交换将ZnO纳米棒转化为ZnSe纳米结构。我们发现,厚的ZnO纳米棒通过ZnSe纳米粒子的营养和生长转化为具有Zns混合ZnSe壳的ZnO / ZnSe核/壳结构,而薄的ZnO纳米棒可以直接模板化纯WZ-ZnSe纳米棒的生长。 ZnO / ZnSe异质结构显示出强烈的绿色发射,这是由于ZnO核中V_(Zn)相关的缺陷复合物引起的。

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