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首页> 外文期刊>Journal of Materials Chemistry, C. materials for optical and electronic devices >Mo-doped GZO films used as anodes or cathodes for highly efficient flexible blue, green and red phosphorescent organic light-emitting diodes
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Mo-doped GZO films used as anodes or cathodes for highly efficient flexible blue, green and red phosphorescent organic light-emitting diodes

机译:钼掺杂的GZO薄膜用作阳极或阴极,用于高效柔性的蓝色,绿色和红色磷光有机发光二极管

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摘要

We propose a novel transparent conductive oxide constructed by doping molybdenum into gallium zinc oxide (GZO). The molybdenum doped GZO (MGZO) on a glass substrate possesses a high average transmittance of 92% in the visible wavelength range, a high work function of 5.08 eV, a low sheet resistance of 37.2 O sq(-1), and an adequate mobility of 2.92 cm(2) V-1 s(-1). Furthermore, the MGZO films on a PET substrate retained a low electrical sheet resistance after 1000 outward bending cycles. By using MGZO films as anodes in conventional blue, green, and red phosphorescent organic light-emitting diodes (OLEDs) on a PET substrate, low turn-on voltages ranging from 2.7 V to 3.1 V could be obtained. Moreover, the EL efficiencies of the conventional blue, green, and red OLEDs, respectively, reached 21.3%, 17.9%, and 8.9%. In addition, flexible MGZO films were further examined as cathodes in blue (green and red) inverted OLEDs, and gave satisfactory performance including a high efficiency of 16.5% (17.5% and 8.5%) and an acceptable turn-on voltage of 3.6 V (3.1 V and 3.4 V). These superior characteristics make MGZO films high-potential candidates as transparent electrodes for future applications in flexible optoelectronics.
机译:我们提出了一种新颖的透明导电氧化物,该氧化物是通过将钼掺杂到氧化锌锌中制成的。玻璃基板上的钼掺杂GZO(MGZO)在可见光波长范围内具有92%的高平均透射率,5.08 eV的高功函,37.2 O sq(-1)的低薄层电阻和足够的迁移率2.92 cm(2)V-1 s(-1)。此外,在1000次向外弯曲循环后,PET基板上的MGZO膜仍保持较低的薄层电阻。通过将MGZO膜用作PET基板上常规的蓝色,绿色和红色磷光有机发光二极管(OLED)中的阳极,可以获得2.7 V至3.1 V的低导通电压。此外,常规的蓝色,绿色和红色OLED的EL效率分别达到21.3%,17.9%和8.9%。此外,还对柔性MGZO薄膜作为蓝色(绿色和红色)倒置OLED中的阴极进行了检查,并给出了令人满意的性能,包括16.5%(17.5%和8.5%)的高效率以及3.6 V( 3.1 V和3.4 V)。这些优异的特性使MGZO膜成为透明电极的潜在潜力,可用于未来在柔性光电中的应用。

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