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首页> 外文期刊>Journal of Materials Chemistry, C. materials for optical and electronic devices >Controllable fabrication of nickel nanoparticle chains based on electrochemical corrosion
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Controllable fabrication of nickel nanoparticle chains based on electrochemical corrosion

机译:基于电化学腐蚀的可控制备镍纳米粒子链

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摘要

The magnetic nanoparticle (NP) chain has attracted great concern due to its potential applications in magnetic recording, electron nano-devices, micro-mechanical sensors, and drug delivery. Here, we demonstrate the controllable preparation of magnetic Ni NP chains using electrochemical corrosion methods. Ni/Cu multi-segmented nanowires (NW) were prepared by alternately depositing Ni and Cu into the pores of an anodic aluminum oxide (AAO) template, then highly uniform Ni NP chains were obtained by immersing Ni/Cu NWs/AAO composite membrane in a 15 wt% NaOH solution for about 50 min. The reaction mechanism is proposed based on electrochemical corrosion, in which Cu serviced as the anode is corroded and Ni serviced as the cathode are retained in the NaOH electrolyte solution. Particle size and separation of the Ni NP chains can be easily adjusted and the smallest particle size and particle spacing reached to 6 nm and 15 nm, respectively. This strategy developed herein can be expected to be general route for the controllable fabrication of metallic NP chains.
机译:磁性纳米粒子(NP)链由于其在磁记录,电子纳米设备,微机械传感器和药物输送中的潜在应用而备受关注。在这里,我们演示了使用电化学腐蚀方法可控地制备磁性Ni NP链。通过将Ni和Cu交替沉积到阳极氧化铝(AAO)模板的孔中来制备Ni / Cu多节纳米线(NW),然后通过将Ni / Cu NWs / AAO复合膜浸入阳极中获得高度均匀的Ni NP链。在15 wt%的NaOH溶液中放置约50分钟。提出了基于电化学腐蚀的反应机理,其中腐蚀了充当阳极的铜,腐蚀了充当阴极的镍。 Ni NP链的粒径和间距可以轻松调节,最小粒径和间距分别达到6 nm和15 nm。可以预期,本文开发的该策略是可控制造金属NP链的一般途径。

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