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Continuous and Discontinuous αTi Layers Between Grains of β(Ti,Co) Phase

机译:β(Ti,Co)相晶粒之间的连续和不连续αTi层

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The microstructure of Ti-Co polycrystals with 1.6 and 3.2 at.% Co has been studied between 690 and 810℃ after long anneals (720-860 h) in the αTi+β(Ti,Co) two-phase area of the Ti-Co phase diagram. It has been observed that depending on the annealing temperature and GB energy, the αTi phase forms either chains of separated lens-like precipitates or continuous uniform layers along β(Ti,Co)/β(Ti,Co) GBs. In other words, β(Ti,Co)/β(Ti,Co)GBs completely or partially wetted by the αTi phase were observed. At 690℃, slightly above eutectoid temperature T_(et) = 685℃, the portion of the completely wetted β(Ti,Co)/β(Ti,Co) GBs is 25% for the Ti-1.6 at.% Co alloy and 60% for the Ti-3.2 at.% Co alloy. It increases with increasing temperature and reaches the maximum of 80% for the Ti-1.6 at.% Co alloy at 780℃ and of 75% for the Ti-3.2 at.% Co alloy at 750℃. At 810℃, i.e., close to the upper border of the αTi + β(Ti,Co) two-phase area of the Ti-Co phase diagram, the portion of the completely wetted β(Ti,Co)/β(Ti,Co) GBs drops down to 40% for the Ti-1.6 at.% Co alloy and 20% for the Ti-3.2 at.% Co alloy. Thus, it has been observed for the first time, that the portion of grain boundaries completely wetted by the layers of a second solid phase can non-monotonously depend on the temperature.
机译:在Ti-α-β+(Ti,Co)两相区经过长时间退火(720-860h)后,研究了Co含量为1.6和3.2at。%的Ti-Co多晶体的微观结构,温度为690-810℃。共相图。已经观察到,取决于退火温度和GB能量,αTi相沿着β(Ti,Co)/β(Ti,Co)GBs形成分离的透镜状沉淀物的链或连续的均匀层。换句话说,观察到被αTi相完全或部分润湿的β(Ti,Co)/β(Ti,Co)GB。在690℃(略高于共析温度T_(et)= 685℃)下,Ti-1.6 at。%Co合金的完全润湿的β(Ti,Co)/β(Ti,Co)GBs的部分为25%, Ti-3.2 at。%Co合金为60%。它随温度升高而增加,在780℃时,Ti-1.6 at。%Co合金的最大值为80%,在750℃时,Ti-3.2 at。%Co合金的最大值为75%。在810℃,即靠近Ti-Co相图的αTi+β(Ti,Co)两相区的上边界,完全润湿的β(Ti,Co)/β(Ti,对于Ti-1.6 at。%Co合金,Co)GBs下降到40%,而对于Ti-3.2 at。Co合金,Co)GBs下降到20%。因此,首次观察到,被第二固相层完全润湿的晶界部分可以非单调地取决于温度。

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