首页> 外文期刊>Journal of Materials Engineering and Performance >Investigation of Synthesized Sulfonated Melamine Formaldehyde as a Novel Corrosion Inhibitor for Mild Steel in Saline Environment
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Investigation of Synthesized Sulfonated Melamine Formaldehyde as a Novel Corrosion Inhibitor for Mild Steel in Saline Environment

机译:盐环境下合成磺化三聚氰胺甲醛对低碳钢缓蚀剂的研究

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A water soluble compound named sulfonated melamine formaldehyde (SMF) was synthesized and its corrosion inhibition behavior was studied for carbon steel in 3.5% NaCl solution by polarization measurements and electrochemical impedance spectroscopy (EIS). SMF was characterized with hydrogen nuclear magnetic resonance spectroscopy and then its physical properties and corrosion prevention efficiencies were investigated. The corrosion behavior of SMF was found to be dependent strongly on the electric nature of functional groups which are present in its structure. The decrease in (i (corr)) and the increase in inhibition efficiency (% IE) with increasing the SMF concentrations proves that it protects C-steel in 3.5% NaCl solution from being corroded and Nyquist diagrams indicate that increasing charge transfer resistance is associated with a decrease in the capacitance and increase in the percentage inhibition efficiency. The decrease in capacitance values could be attributed to the adsorption of the inhibitor molecules at the metal surface by increasing the concentration of inhibitor in the solution the inhibition efficiency increased and the best inhibition was obtained at 1000 ppm inhibitor concentration. The scanning electron microscope was used to investigate the surface morphology of specimens in the absence and presence of inhibitor compound.
机译:合成了一种水溶性化合物磺化三聚氰胺甲醛(SMF),并通过极化测量和电化学阻抗谱(EIS)研究了其在3.5%NaCl溶液中对碳钢的缓蚀性能。用氢核磁共振光谱对SMF进行了表征,然后研究了其物理性质和防腐效果。发现SMF的腐蚀行为在很大程度上取决于其结构中存在的官能团的电性质。随着SMF浓度的增加(i(corr))的降低和抑制效率的提高(%IE)证明了它可以保护3.5%NaCl溶液中的C钢不被腐蚀,奈奎斯特图表明与电荷转移阻力的增加相关电容减小,抑制率提高。电容值的下降可归因于通过增加溶液中抑制剂的浓度,抑制剂分子在金属表面的吸附,抑制效率提高,在抑制剂浓度为1000 ppm时获得了最佳的抑制作用。扫描电子显微镜用于研究在不存在和不存在抑制剂化合物的情况下样品的表面形态。

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