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Effect of Boron and Cerium on Corrosion Resistance of Cu-Fe-P Alloy

机译:硼和铈对Cu-Fe-P合金耐蚀性的影响

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摘要

The effects of B and Ce on the corrosion resistance of Cu-0.22Fe-0.06P alloy were investigated by salt spray and electrochemical tests. The corrosion morphology was studied by scanning electron microscopy. The corrosion products were characterized by energy-dispersive x-ray spectroscopy and x-ray diffraction analysis. The impurity content was determined by inductively coupled plasma mass spectrometry. The conductivity was measured using an eddy current conductivity meter. The grains of Cu-0.22Fe-0.06P alloy were refined by the addition of B and Ce. The electrochemical corrosion process of alloy is retarded due to purification effect of B and Ce. After the addition of a trace amount of B, the corrosion resistance of the alloy decreased. The corrosion resistance of Cu-0.22Fe-0.06P-0.025B-0.05Ce was better than that of Cu-0.22Fe-0.06P-0.025B due to the fact that the purification effect of Ce is better than that of B. The main corrosion products of the Cu-Fe-P alloys in a NaCl solution are Cu2Cl(OH)(3) and Cu2O. The addition of trace amounts of B and Ce did not change the components of the corrosion product.
机译:通过盐雾和电化学测试研究了B和Ce对Cu-0.22Fe-0.06P合金耐蚀性的影响。通过扫描电子显微镜研究腐蚀形态。通过能量色散X射线光谱和X射线衍射分析来表征腐蚀产物。杂质含量通过电感耦合等离子体质谱法测定。使用涡流电导仪测量电导率。通过添加B和Ce可以细化Cu-0.22Fe-0.06P合金的晶粒。合金的电化学腐蚀过程由于B和Ce的净化作用而受到阻碍。添加微量的B后,合金的耐腐蚀性降低。 Cu-0.22Fe-0.06P-0.025B-0.05Ce的耐蚀性优于Cu-0.22Fe-0.06P-0.025B,这是由于Ce的提纯效果优于B。在NaCl溶液中,Cu-Fe-P合金的主要腐蚀产物是Cu2Cl(OH)(3)和Cu2O。痕量的B和Ce的添加不会改变腐蚀产物的成分。

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