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首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >Effects of thermal conversion on the metal/polymer interface of layer-by-layer PPV/DBS films
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Effects of thermal conversion on the metal/polymer interface of layer-by-layer PPV/DBS films

机译：热转换对逐层PPV / DBS膜的金属/聚合物界面的影响

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摘要

in this paper, the thermal conversion effects on the metal/polymer interface of poly(p-phenylene vinylene) (PPV) films were investigated. The substrates studied were: aluminum, indium tin oxide, gold and glass-(BK7). Layer-by-layer PPV films were processed from poly(xylylidene tetrahydrothiophenium chloride) and dodecylbenzenesulfonate with 5 and 20 layers. The thermal conversion treatment was performed at 110 degrees C and 230 degrees C. The films were investigated through emission spectra. Selectively, the emission occurred in large PPV segments and it showed a significant dependence on the film/metal interface. It was clear that this synthesis process reduced the metal degradation in the interface. The Huang-Rhys factor was estimated to demonstrate this effect. (c) 2006 Elsevier B.V. All rights reserved.
机译：本文研究了热转化对聚对亚苯基亚乙烯基（PPV）薄膜金属/聚合物界面的影响。研究的基材为：铝，氧化铟锡，金和玻璃-（BK7）。由聚（亚二甲苯基四氢噻吩鎓氯化物）和十二烷基苯磺酸盐（具有5层和20层）加工而成的逐层PPV膜。在110℃和230℃下进行热转化处理。通过发射光谱研究膜。选择性地，发射发生在大的PPV段中，并且显示出对膜/金属界面的显着依赖性。显然，该合成过程减少了界面中的金属降解。估计Huang-Rhys因子可以证明这种效果。 （c）2006 Elsevier B.V.保留所有权利。

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