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Magnetic properties of TiCx/C nanocomposites

机译:TiCx / C纳米复合材料的磁性能

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The magnetic properties of nanocrystalline titanium carbide dispersed in a carbon matrix (TiCx/C) prepared by the non-hydrolytic sot-gel process have been studied by dc magnetization measurements. The superconducting phase of titanium carbide has been observed at low temperatures with the onset of the superconducting transition temperature T-c at about 3.5 K, superimposed on a ferromagrietic component. At T > T-c the magnetic response of TiCx /C is determined by the interplay of the ferromagnetic contribution with the paramagnetic/diamagnetic signal of the metallic system and the contribution of exchange coupled paramagnetic ions. Moreover, significant differences are observed in the magnetic response for samples of the same preparation batch, indicative of the magnetic/electronic inhomogeneity of nanocrystalline titanium carbide which is important for its practical applications. Published by Elsevier B.V.
机译:通过直流磁化测量研究了分散在通过非水解溶胶凝胶法制备的碳基体(TiCx / C)中的纳米晶碳化钛的磁性。在低温下观察到碳化钛的超导相,超导转变温度T-c的起始温度约为3.5 K,并叠加在铁磁材料上。在T> T-c时,TiCx / C的磁响应由铁磁贡献与金属系统的顺磁性/反磁性信号以及交换耦合顺磁性离子的贡献相互作用决定。此外,对于同一制备批次的样品,在磁响应方面观察到显着差异,这表明纳米晶碳化钛的磁/电子不均匀性对其实际应用很重要。由Elsevier B.V.发布

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