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The luminescence properties of Dy-doped high silicate glass

机译:掺Dy高硅酸盐玻璃的发光特性

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摘要

The visible luminescence of silicate glass (SiO2 (> 70%)-R2O3[B2O3, Al2O3]-RO[ZnO, MgO, CaO, BaO]-R2O[Na2O, K2O]) doped with various concentrations of dysprosium was investigated. The emission, excitation and absorption spectra, as well as kinetic parameters, were measured over a temperature range from 20 to 300 K. The Judd-Ofelt analysis was applied to the data, in order to calculate transition rates and branching ratios for all observed emission bands. Concentration quenching was experimentally observed at a Dy ion concentration higher than 8 x 10(19) cm(-3) and explained by an analytical model based on the Inokuti-Hirayama theory. The quantum efficiency of visible luminescence and the stimulated emission cross-section at 570 nm were (85 +/- 50% and (3.4 +/- 0.4) x 10(-21) cm(2), respectively. (C) 1997 Elsevier Science B.V.
机译:研究了掺入不同浓度的硅酸盐玻璃(SiO2(> 70%)-R2O3 [B2O3,Al2O3] -RO [ZnO,MgO,CaO,BaO] -R2O [Na2O,K2O]的可见光。在20至300 K的温度范围内测量了发射光谱,激发光谱和吸收光谱以及动力学参数。对数据进行了Judd-Ofelt分析,以计算所有观察到的发射的跃迁速率和支化比。乐队。在高于8 x 10(19)cm(-3)的Dy离子浓度下实验观察到浓度猝灭,并通过基于Inokuti-Hirayama理论的分析模型进行了解释。可见光的量子效率和570 nm处的受激发射截面分别是(85 +/- 50%)和(3.4 +/- 0.4)x 10(-21)cm(2)。(C)1997 Elsevier科学BV

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