Characterization of the structure of binary zinc ultraphosphate glasses by infrared and Raman spectroscopy

Meyer K

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Characterization of the structure of binary zinc ultraphosphate glasses by infrared and Raman spectroscopy

机译：红外和拉曼光谱表征二元超磷酸锌玻璃的结构

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摘要

The Raman and infrared spectra of zinc phosphate glasses, xZnO .(1 - x)P2O5 with 0 less than or equal to x less than or equal to 0.5, and the crystalline compounds o'-P2O5,ZnP4O11,alpha(1)-,alpha(2)-, and beta-Zn(PO3)(2) were measured. An analysis of the vibrational spectra is discussed in comparison with the results of the investigation of the same glasses by P-31-MAS-NMR spectroscopy and X-ray diffraction. The structure of the zinc phosphate glasses can be described by substructures of the high-temperature modifications of the three crystalline compounds with x = 0, 0.33, and 0.5.

机译：磷酸锌玻璃xZnO。（1- -x）P2O5的拉曼光谱和红外光谱，0小于或等于x小于或等于0.5，以及结晶化合物o'-P2O5，ZnP4O11，alpha（1）-，测量了alpha（2）-和beta-Zn（PO3）（2）。与通过P-31-MAS-NMR光谱和X射线衍射对相同玻璃的研究结果进行比较，讨论了振动光谱的分析。磷酸锌玻璃的结构可以通过x ＝ 0、0.33和0.5的三种结晶化合物的高温变体的子结构来描述。

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |1997年第3期|共13页
作者
Meyer K;
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正文语种 eng
中图分类晶体学;
关键词
SHORT-RANGE STRUCTURE; PHOSPHATE-GLASSES; CRYSTAL-STRUCTURE;

机译：短程结构;磷酸盐玻璃;晶体结构;

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1. Characterization of the structure of binary zinc ultraphosphate glasses by infrared and Raman spectroscopy [J] . Meyer K Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 1997,第3期

机译：红外和拉曼光谱表征二元超磷酸锌玻璃的结构
2. Structural characterisation of binary magnesium ultraphosphate glasses by vibrational spectroscopy [J] . K. Meyer European Journal of Glass Science and Technology, PartB. Physics and Chemistry of Glasses . 2001,第2期

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3. Local structure of zinc ultraphosphate glasses containing large amount of hydroxyl groups: P-31 and H-1 solid state nuclear magnetic resonance investigation [J] . Mercier C., Sfihi H., Palavit G., Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 1998,第2期

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Characterization of the structure of binary zinc ultraphosphate glasses by infrared and Raman spectroscopy

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