Electrochemical determination of reduction potentials in glass-forming melts

Medlin MW.; Schreiber HD.; Sienerth KD.

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Electrochemical determination of reduction potentials in glass-forming melts

机译：电化学测定玻璃熔体中还原电位的方法

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Square-wave voltammetry (SWV) has been used to determine the reduction potentials of several multivalent elements in situ in an alkali borosilicate melt. Such reduction potentials measured at melt temperature were found to be proportional to the relative reduction potentials obtained from analyses of the quenched glasses. Accordingly, the redox state of the glass typically reflects the redox state of the melt. Although SWV is a sensitive tool for monitoring the total concentration of specific multivalent elements in the melt, the method does not directly monitor the redox state of the melt. (C) 1998 Elsevier Science B.V. All rights reserved. [References: 23]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |1998年第3期|共9页
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Medlin MW.; Schreiber HD.; Sienerth KD.;
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正文语种 eng
中图分类晶体学;
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Square-wave voltammetry; Polyvalent elements; Redox behavior; Molten glass; Ions; Silicate; Iron;

机译：方波伏安法;多元元素;氧化还原行为;熔融玻璃;离子;硅酸盐;铁;

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1. Electrochemical determination of reduction potentials in glass-forming melts [J] . Medlin MW., Schreiber HD., Sienerth KD. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 1998,第1a3期

机译：电化学测定玻璃熔体中还原电位的方法
2. Potentials of Iron and Oxygen Production by Direct Electrochemical Reduction of Oxides in Ionic Melts [J] . P. Ra?ka, ?. Langová, J. Le?ko Chemicke Listy . 2014,第6期

机译：直接电化学还原离子熔体中氧化物产生铁和氧气的潜力
3. Potentials of Iron and Oxygen Production by Direct Electrochemical Reduction of Oxides in Ionic Melts [J] . J. Le?ko, P. Ra?ka ?. Langová Chemicke Listy . 2014,第06期

机译：直接电化学还原离子熔体中氧化物产生铁和氧气的潜力
4. THE CRITERIA OF HYDROGEN AND OXYGEN POTENTIALS IN COPPER MELT FOR MAKING A SOUND CASTING OF BAR AND ROD -THE GUIDE OF THE EFFECTIVE USE OF AN ELECTROCHEMICAL GAS MONITORING SYSTEM- [C] . Norihiko Fukatsu, Noriaki Kurita, Daisuke Yamamoto Yazawa International Symposium on Metallurgical and Materials Processing: Principles and Technologies Vol.1 Materials Processing Fundamentals and New Technologies, Mar 2-6, 2003, San Diego, California USA . 2003

机译：用于制作棒材和棒材的铜熔体中氢和氧势的判据-电化学气体监测系统的有效使用指南
5. Oxygen reduction in lithium carbonate melt: Determination of electrode kinetic and mass transfer parameters. [D] . Dave, Bhasker Bhagirath. 1991

机译：碳酸锂熔体中的氧还原：电极动力学和传质参数的测定。
6. Determination of Activation Overpotential during the Nucleation of Hcp-Cobalt Nanowires Synthesized by Potentio-Static Electrochemical Reduction [O] . Ryusei Saeki, Takeshi Ohgai 2018

机译：恒电位电化学还原法合成Hcp-钴纳米线成核过程中活化超电势的测定
7. Electrochemical Reduction of Undoped and Cobalt-Doped BiFeO3 Induced by Water Exposure: Quantitative Determination of Reduction Potentials and Defect Energy Levels Using Photoelectron Spectroscopy [O] . Nicole S. Bein, Pamela Machado, Mariona Coll, 2019

机译：水暴露诱导的未掺杂和掺杂的BifeO3的电化学减少：使用光电子谱的定量测定降低电位和缺陷能量水平
8. Electrochemical Reduction of Oxygen in Carbonate and Carbonate-Halide Melts. [R] . lorenz, p. k. janz, g. j. 1971

机译：碳酸盐和碳酸盐 - 卤化物熔体中氧的电化学还原。

Electrochemical determination of reduction potentials in glass-forming melts

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