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Characterization of rare earth aluminosilicate glasses

机译:稀土铝硅酸盐玻璃的表征

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摘要

Rare earth glasses are commonly used in lasers, sensors and radiation shield glasses. Rare earth aluminosilicate-based glasses have been successfully used as in vivo radiation delivery vehicles, in treatment of primary hepatocellular carcinoma, irradiation of diseased synovial membrane for the treatment of rheumatoid arthritis, and treatment of prostate tumors. These glasses have also been found useful to promote liquid-phase sintering of covalent ceramics and, specifically, silicon carbide-based ceramics. Usually, the SiO2-Al2O3-RE2O3 system is used as sintering additives. In this work, several rare earth silicate glasses (RE = Y, La, Nd, Dy and Yb) were prepared based on 60%SiO2-20%Al2O3-20%RE2O3 (mol%) compositions. These glasses were characterized by infrared spectroscopy and nuclear magnetic resonance. Moreover, the liquid phase sintering of silicon carbide ceramics was studied using dilatometric experiments with 10 vol.% additives of the 60%SiO2-20%Al2O3-20%RE2O3 system. © 2005 Elsevier B.V. All rights reserved.
机译:稀土玻璃通常用于激光器,传感器和辐射屏蔽玻璃中。基于稀土铝硅酸盐的玻璃已成功地用作体内放射输送工具,用于治疗原发性肝细胞癌,辐照患病的滑膜以治疗类风湿性关节炎和治疗前列腺肿瘤。还发现这些玻璃可用于促进共价陶瓷,特别是碳化硅基陶瓷的液相烧结。通常,SiO 2 -Al 2 O 3 -RE 2 O 3体系用作烧结添加剂。在这项工作中,基于60%SiO2-20%Al2O3-20%RE2O3(mol%)组成制备了几种稀土硅酸盐玻璃(RE = Y,La,Nd,Dy和Yb)。这些玻璃的特征在于红外光谱和核磁共振。此外,使用膨胀试验,使用60%SiO2-20%Al2O3-20%RE2O3体系的10%(体积)添加剂,对碳化硅陶瓷的液相烧结进行了研究。 &复制; 2005 Elsevier B.V.保留所有权利。

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