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Er3+ doped glasses: Correlating the glass composition with spectroscopic properties and with the local symmetry of the Er site

机译:掺Er3 +的玻璃:使玻璃成分与光谱性质和Er位置的局部对称性相关

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摘要

Rare earth doped glasses are of increasing importance for laser applications and for optical communication. Especially Er3+ doped glasses with their transition at 1530 nm are a key component for optical telecommunication applications. The optical transitions within the 4f states of the rare earth ions are only weakly dependent on the surrounding crystal field. This weak dependence of the spectral properties can be observed as a function of glass composition. Judd-Ofelt theory uses the deviation from spherical symmetry of the Er3+ site as a perturbation. Applying a Judd-Ofelt analysis the glass composition can be systematically correlated with spectral properties, Judd-Ofelt parameters and properties of an optical amplifier. We show that a detailed tailoring of spectroscopic properties via the glass composition is possible and identify key components to selectively influence amplifier performance. (c) 2005 Elsevier B.V. All rights reserved.
机译:掺杂稀土的玻璃对于激光应用和光通信越来越重要。尤其是掺有Er3 +的玻璃,它们在1530 nm处的跃迁是光学电信应用的关键组件。稀土离子在4f态内的光学跃迁仅微弱地取决于周围的晶体场。光谱性质的这种弱依赖性可以作为玻璃成分的函数观察到。 Judd-Ofelt理论使用与Er3 +位点的球形对称性的偏差作为扰动。应用Judd-Ofelt分析,可以将玻璃成分与光谱特性,Judd-Ofelt参数和光学放大器的特性进行系统关联。我们表明,通过玻璃成分对光谱特性进行详细的剪裁是可能的,并且可以确定关键成分以选择性地影响放大器的性能。 (c)2005 Elsevier B.V.保留所有权利。

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